Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone

Yukino Shinomoto, Akira Yoshimura, Hisato Shimizu, Mutsumi Yamazaki, Viktor V. Zhdankin, Akio Saito

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.

Original languageEnglish
Pages (from-to)5212-5215
Number of pages4
JournalOrganic Letters
Volume17
Issue number21
DOIs
Publication statusPublished - 6 Nov 2015
Externally publishedYes

Fingerprint

Azides
Iodides
aldehydes
Aldehydes
iodides
room temperature
Temperature

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone. / Shinomoto, Yukino; Yoshimura, Akira; Shimizu, Hisato; Yamazaki, Mutsumi; Zhdankin, Viktor V.; Saito, Akio.

In: Organic Letters, Vol. 17, No. 21, 06.11.2015, p. 5212-5215.

Research output: Contribution to journalArticle

Shinomoto, Yukino ; Yoshimura, Akira ; Shimizu, Hisato ; Yamazaki, Mutsumi ; Zhdankin, Viktor V. ; Saito, Akio. / Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone. In: Organic Letters. 2015 ; Vol. 17, No. 21. pp. 5212-5215.
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