Abstract
In order to test the suitability of newly developed wall-jet electrochemical cells FC2 for detection of electrochemically active biomarkers, electrochemical efficiency of those cells have been characterized using [Fe (CN)6]3-/[Fe(CN)6]4- redox couple as a probe. Measurements were performed in the range of Reynolds numbers from 0.067 to 21.3 for flow rates 0.1 - 32 ml/hr. Efficiency of the cells were found to be in the range of 0.06 - 5.3 %. The dependence of efficiency E on the flow rate Q follows the equation E (%) = a x Q b (a = 0.855, b = - 0.746;[Q] = ml/hr) with R = 0,999. The difference between the three cells can be characterized by SD of a and b (8.2 % and 5.2 %, respectively). The dependence of current I (nA) on the flow rate Q follows the same equation I(nA) = a · Qb with a = 2294 and b = 0,255 (SD = 8.2 % and 14.7 % for a and b, respectively). FC2 cell with wall-jet hydrodynamics provides reproducible electrochemical measurements with well-defined efficiency and current flow dependence.
| Original language | English |
|---|---|
| Pages (from-to) | 4922-4927 |
| Number of pages | 6 |
| Journal | International Journal of Electrochemical Science |
| Volume | 10 |
| Issue number | 6 |
| Publication status | Published - 1 Jan 2015 |
| Externally published | Yes |
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Keywords
- Efficiency
- Electrochemical cell
- Flow analysis
- Wall-jet detector
ASJC Scopus subject areas
- Electrochemistry
Cite this
Testing of electrochemical efficiency of wall-jet cell FC2 as a tool for detection of electrochemically oxidisable biomarkers. / Krejčí, Jan; Ventrubová, Iva; Ježová, Lucie; Fischer, Jan; Barek, Jiří.
In: International Journal of Electrochemical Science, Vol. 10, No. 6, 01.01.2015, p. 4922-4927.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Testing of electrochemical efficiency of wall-jet cell FC2 as a tool for detection of electrochemically oxidisable biomarkers
AU - Krejčí, Jan
AU - Ventrubová, Iva
AU - Ježová, Lucie
AU - Fischer, Jan
AU - Barek, Jiří
PY - 2015/1/1
Y1 - 2015/1/1
N2 - In order to test the suitability of newly developed wall-jet electrochemical cells FC2 for detection of electrochemically active biomarkers, electrochemical efficiency of those cells have been characterized using [Fe (CN)6]3-/[Fe(CN)6]4- redox couple as a probe. Measurements were performed in the range of Reynolds numbers from 0.067 to 21.3 for flow rates 0.1 - 32 ml/hr. Efficiency of the cells were found to be in the range of 0.06 - 5.3 %. The dependence of efficiency E on the flow rate Q follows the equation E (%) = a x Q b (a = 0.855, b = - 0.746;[Q] = ml/hr) with R = 0,999. The difference between the three cells can be characterized by SD of a and b (8.2 % and 5.2 %, respectively). The dependence of current I (nA) on the flow rate Q follows the same equation I(nA) = a · Qb with a = 2294 and b = 0,255 (SD = 8.2 % and 14.7 % for a and b, respectively). FC2 cell with wall-jet hydrodynamics provides reproducible electrochemical measurements with well-defined efficiency and current flow dependence.
AB - In order to test the suitability of newly developed wall-jet electrochemical cells FC2 for detection of electrochemically active biomarkers, electrochemical efficiency of those cells have been characterized using [Fe (CN)6]3-/[Fe(CN)6]4- redox couple as a probe. Measurements were performed in the range of Reynolds numbers from 0.067 to 21.3 for flow rates 0.1 - 32 ml/hr. Efficiency of the cells were found to be in the range of 0.06 - 5.3 %. The dependence of efficiency E on the flow rate Q follows the equation E (%) = a x Q b (a = 0.855, b = - 0.746;[Q] = ml/hr) with R = 0,999. The difference between the three cells can be characterized by SD of a and b (8.2 % and 5.2 %, respectively). The dependence of current I (nA) on the flow rate Q follows the same equation I(nA) = a · Qb with a = 2294 and b = 0,255 (SD = 8.2 % and 14.7 % for a and b, respectively). FC2 cell with wall-jet hydrodynamics provides reproducible electrochemical measurements with well-defined efficiency and current flow dependence.
KW - Efficiency
KW - Electrochemical cell
KW - Flow analysis
KW - Wall-jet detector
UR - http://www.scopus.com/inward/record.url?scp=84930174601&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84930174601&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:84930174601
VL - 10
SP - 4922
EP - 4927
JO - International Journal of Electrochemical Science
JF - International Journal of Electrochemical Science
SN - 1452-3981
IS - 6
ER -