Abstract
The experiment results on temperature dependence of stationary intensity of PL (photoluminescence) and RRL (radical recombination luminescence) of ZnS-Cu and ZnSAg bands excited by hydrogen atoms are being discussed. It was established that the temperatures curves of corresponding PL and RRL ZnS-Cu and ZnS-Ag bands are appreciately different The temperature curves of PL ZnS-Cu and ZnS-Ag are the conventional curves of luminescence temperature extinguishing. The temperature curves of RRL ZnS-Cu blue and green bands have a maximum and are strongly different from those of PL. Temperature dependence of RRL ZnS-Cu light-blue and green bands are monotonous (like PL) but more sharply following down curves. The observed discrepancy of temperature dependendence of RRL and PL ZnS-Cu and ZnS Ag bands is due to the fact that in case of RRL opposite to volume photo excitation (the excitation depth is sufficiently great 1 mkm), the excited flashing centers are distributed either on the surface or inside a thin surface layer of the thickness not greater than several lattice parameters. Thus the discrepancy between RRL and PL is due to adsorption-deadsorption process on the interface of a crystal phospho It was proved that during atomic excitation luminescence as well as photoluminescence, the recombination interaction of flashing centers dominates. It leads with temperature to depositing of greater part of energy in long wave bands. In the process of RRL in comparison with PL, that effect is much greater.
| Original language | English |
|---|---|
| Title of host publication | 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004 |
| Pages | 282-285 |
| Number of pages | 4 |
| Volume | 2 |
| Publication status | Published - 2004 |
| Event | 8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 - Tomsk, Russian Federation Duration: 26 Jun 2004 → 3 Jul 2004 |
Other
| Other | 8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 26.6.04 → 3.7.04 |
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Keywords
- Adsorption
- Excitation dependence
- Hydrogen
- Interaction
- Luminescence
- Molecules
- Phosphors
- Recombination
- Surfase
ASJC Scopus subject areas
- Engineering(all)
Cite this
Temperature dependence of radical recombination luminescence of zinc-sulfur crystalline phosphors. / Tyurin, Yu I.; Sivov, Yu A.; Khoruzhi, V. D.
8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. Vol. 2 2004. p. 282-285.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Temperature dependence of radical recombination luminescence of zinc-sulfur crystalline phosphors
AU - Tyurin, Yu I.
AU - Sivov, Yu A.
AU - Khoruzhi, V. D.
PY - 2004
Y1 - 2004
N2 - The experiment results on temperature dependence of stationary intensity of PL (photoluminescence) and RRL (radical recombination luminescence) of ZnS-Cu and ZnSAg bands excited by hydrogen atoms are being discussed. It was established that the temperatures curves of corresponding PL and RRL ZnS-Cu and ZnS-Ag bands are appreciately different The temperature curves of PL ZnS-Cu and ZnS-Ag are the conventional curves of luminescence temperature extinguishing. The temperature curves of RRL ZnS-Cu blue and green bands have a maximum and are strongly different from those of PL. Temperature dependence of RRL ZnS-Cu light-blue and green bands are monotonous (like PL) but more sharply following down curves. The observed discrepancy of temperature dependendence of RRL and PL ZnS-Cu and ZnS Ag bands is due to the fact that in case of RRL opposite to volume photo excitation (the excitation depth is sufficiently great 1 mkm), the excited flashing centers are distributed either on the surface or inside a thin surface layer of the thickness not greater than several lattice parameters. Thus the discrepancy between RRL and PL is due to adsorption-deadsorption process on the interface of a crystal phospho It was proved that during atomic excitation luminescence as well as photoluminescence, the recombination interaction of flashing centers dominates. It leads with temperature to depositing of greater part of energy in long wave bands. In the process of RRL in comparison with PL, that effect is much greater.
AB - The experiment results on temperature dependence of stationary intensity of PL (photoluminescence) and RRL (radical recombination luminescence) of ZnS-Cu and ZnSAg bands excited by hydrogen atoms are being discussed. It was established that the temperatures curves of corresponding PL and RRL ZnS-Cu and ZnS-Ag bands are appreciately different The temperature curves of PL ZnS-Cu and ZnS-Ag are the conventional curves of luminescence temperature extinguishing. The temperature curves of RRL ZnS-Cu blue and green bands have a maximum and are strongly different from those of PL. Temperature dependence of RRL ZnS-Cu light-blue and green bands are monotonous (like PL) but more sharply following down curves. The observed discrepancy of temperature dependendence of RRL and PL ZnS-Cu and ZnS Ag bands is due to the fact that in case of RRL opposite to volume photo excitation (the excitation depth is sufficiently great 1 mkm), the excited flashing centers are distributed either on the surface or inside a thin surface layer of the thickness not greater than several lattice parameters. Thus the discrepancy between RRL and PL is due to adsorption-deadsorption process on the interface of a crystal phospho It was proved that during atomic excitation luminescence as well as photoluminescence, the recombination interaction of flashing centers dominates. It leads with temperature to depositing of greater part of energy in long wave bands. In the process of RRL in comparison with PL, that effect is much greater.
KW - Adsorption
KW - Excitation dependence
KW - Hydrogen
KW - Interaction
KW - Luminescence
KW - Molecules
KW - Phosphors
KW - Recombination
KW - Surfase
UR - http://www.scopus.com/inward/record.url?scp=29144474651&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=29144474651&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:29144474651
SN - 0780383834
SN - 9780780383838
VL - 2
SP - 282
EP - 285
BT - 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004
ER -