Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes

Roman D. Marchenko, Anna A. Lysova, Denis G. Samsonenko, Danil N. Dybtsev, Andrei S. Potapov

Research output: Contribution to journalArticle

Abstract

A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

Original languageEnglish
Article number114330
JournalPolyhedron
Volume177
DOIs
Publication statusPublished - 1 Feb 2020

Fingerprint

Alkanes
coordination polymers
Cadmium
Silver
Paraffins
cadmium
alkanes
Nitrates
Polymers
Ligands
silver
Acetone
Acetonitrile
acetone
ligands
acetonitrile
nitrates
synthesis
Klebsiella
pneumonia

Keywords

  • Benzotriazole
  • Cadmium
  • Coordination polymers
  • Crystal structure
  • Silver

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes. / Marchenko, Roman D.; Lysova, Anna A.; Samsonenko, Denis G.; Dybtsev, Danil N.; Potapov, Andrei S.

In: Polyhedron, Vol. 177, 114330, 01.02.2020.

Research output: Contribution to journalArticle

@article{d966d57f519548aea423fe7f0bbc2754,
title = "Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes",
abstract = "A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.",
keywords = "Benzotriazole, Cadmium, Coordination polymers, Crystal structure, Silver",
author = "Marchenko, {Roman D.} and Lysova, {Anna A.} and Samsonenko, {Denis G.} and Dybtsev, {Danil N.} and Potapov, {Andrei S.}",
year = "2020",
month = "2",
day = "1",
doi = "10.1016/j.poly.2019.114330",
language = "English",
volume = "177",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes

AU - Marchenko, Roman D.

AU - Lysova, Anna A.

AU - Samsonenko, Denis G.

AU - Dybtsev, Danil N.

AU - Potapov, Andrei S.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

AB - A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

KW - Benzotriazole

KW - Cadmium

KW - Coordination polymers

KW - Crystal structure

KW - Silver

UR - http://www.scopus.com/inward/record.url?scp=85077316469&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85077316469&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.114330

DO - 10.1016/j.poly.2019.114330

M3 - Article

AN - SCOPUS:85077316469

VL - 177

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 114330

ER -