Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2

E. V. Ilyina, I. V. Mishakov, A. A. Vedyagin, A. F. Bedilo, K. J. Klabunde

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The developed method for synthesis of binary VOx/MgO aerogels by hydrolysis of the V and Mg alkoxides mixed together followed by gelation and supercritical drying makes it possible to obtain aerogels with exceptionally high surface areas (~ 1200 m2/g) and uniform vanadium distribution. Their dehydration yields nanocrystalline VOx/MgO with nanoparticle size ca. 5 nm. The synthesized nanocrystalline VOx/MgO oxides were used as destructive sorbents for decomposition of halocarbons. The doping of MgO aerogels with a small amount of VOx (1-2%) results in significant acceleration of the reaction with CF 2Cl2 causing deeper MgO transformation to MgF2 and shortening the induction period.

Original languageEnglish
Title of host publicationNanotechnology 2010
Subtitle of host publicationAdvanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Pages452-455
Number of pages4
Volume1
Publication statusPublished - 2010
Externally publishedYes
EventNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 - Anaheim, CA, United States
Duration: 21 Jun 201024 Jun 2010

Conference

ConferenceNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
CountryUnited States
CityAnaheim, CA
Period21.6.1024.6.10

Fingerprint

Aerogels
aerogels
Adsorption
adsorption
synthesis
Halocarbons
halocarbons
Vanadium
sorbents
alkoxides
gelation
Gelation
Sorbents
Dehydration
dehydration
Oxides
vanadium
drying
hydrolysis
Hydrolysis

Keywords

  • Aerogels
  • Destructive sorption
  • Halocarbons
  • Nanocrystalline oxides
  • VO /MgO

ASJC Scopus subject areas

  • Ceramics and Composites
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Ilyina, E. V., Mishakov, I. V., Vedyagin, A. A., Bedilo, A. F., & Klabunde, K. J. (2010). Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. In Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 (Vol. 1, pp. 452-455)

Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. / Ilyina, E. V.; Mishakov, I. V.; Vedyagin, A. A.; Bedilo, A. F.; Klabunde, K. J.

Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Vol. 1 2010. p. 452-455.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ilyina, EV, Mishakov, IV, Vedyagin, AA, Bedilo, AF & Klabunde, KJ 2010, Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. in Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. vol. 1, pp. 452-455, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010, Anaheim, CA, United States, 21.6.10.
Ilyina EV, Mishakov IV, Vedyagin AA, Bedilo AF, Klabunde KJ. Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. In Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Vol. 1. 2010. p. 452-455
Ilyina, E. V. ; Mishakov, I. V. ; Vedyagin, A. A. ; Bedilo, A. F. ; Klabunde, K. J. / Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Vol. 1 2010. pp. 452-455
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