Synthesis of motor fuels from bioethanol

V. F. Tret'yakov, A. S. Lermontov, Yu I. Makarfi, M. S. Yakimova, N. A. Frantsuzova, L. M. Koval', V. I. Erofeev

Division for Oil and Gas Engineering

Research output: Contribution to journal › Article

Abstract

A study was conducted to demonstrate the synthesis of motor fuels from bioethanol. The conversion mechanism included the dehydration of ethanol with isomerization and ring closure in the hydrocarbon fragments or hydrogenation. It was observed during the study that the conversion of ethanol can be affected by process parameters like temperature, pressure, and raw material feed rate. It was also found that the conversion of ethanol on catalysts based on high-silica ZSM-5 zeolites with silicate modulus Si:Al > 100 produced gas with ethylene and olefins. Conversion of ethanol on oxygen zeolites with Si:Al < 80 produced a liquid product as a mixture of aromatic, saturated, and olefinic hydrocarbons. Catalytic conversion of ethanol by biomass fermentation can be used as an alternative for oil refining and to reduce the carbon dioxide emission.

Original language	English
Pages (from-to)	409-414
Number of pages	6
Journal	Chemistry and Technology of Fuels and Oils
Volume	44
Issue number	6
DOIs	https://doi.org/10.1007/s10553-009-0077-y
Publication status	Published - Nov 2008

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ASJC Scopus subject areas

Chemical Engineering(all)
Chemistry(all)
Fuel Technology
Energy Engineering and Power Technology

Cite this

Tret'yakov, V. F., Lermontov, A. S., Makarfi, Y. I., Yakimova, M. S., Frantsuzova, N. A., Koval', L. M., & Erofeev, V. I. (2008). Synthesis of motor fuels from bioethanol. Chemistry and Technology of Fuels and Oils, 44(6), 409-414. https://doi.org/10.1007/s10553-009-0077-y

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abstract = "A study was conducted to demonstrate the synthesis of motor fuels from bioethanol. The conversion mechanism included the dehydration of ethanol with isomerization and ring closure in the hydrocarbon fragments or hydrogenation. It was observed during the study that the conversion of ethanol can be affected by process parameters like temperature, pressure, and raw material feed rate. It was also found that the conversion of ethanol on catalysts based on high-silica ZSM-5 zeolites with silicate modulus Si:Al > 100 produced gas with ethylene and olefins. Conversion of ethanol on oxygen zeolites with Si:Al < 80 produced a liquid product as a mixture of aromatic, saturated, and olefinic hydrocarbons. Catalytic conversion of ethanol by biomass fermentation can be used as an alternative for oil refining and to reduce the carbon dioxide emission.",

author = "Tret'yakov, {V. F.} and Lermontov, {A. S.} and Makarfi, {Yu I.} and Yakimova, {M. S.} and Frantsuzova, {N. A.} and Koval', {L. M.} and Erofeev, {V. I.}",

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AU - Tret'yakov, V. F.

AU - Lermontov, A. S.

AU - Makarfi, Yu I.

AU - Yakimova, M. S.

AU - Frantsuzova, N. A.

AU - Koval', L. M.

AU - Erofeev, V. I.

PY - 2008/11

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N2 - A study was conducted to demonstrate the synthesis of motor fuels from bioethanol. The conversion mechanism included the dehydration of ethanol with isomerization and ring closure in the hydrocarbon fragments or hydrogenation. It was observed during the study that the conversion of ethanol can be affected by process parameters like temperature, pressure, and raw material feed rate. It was also found that the conversion of ethanol on catalysts based on high-silica ZSM-5 zeolites with silicate modulus Si:Al > 100 produced gas with ethylene and olefins. Conversion of ethanol on oxygen zeolites with Si:Al < 80 produced a liquid product as a mixture of aromatic, saturated, and olefinic hydrocarbons. Catalytic conversion of ethanol by biomass fermentation can be used as an alternative for oil refining and to reduce the carbon dioxide emission.

AB - A study was conducted to demonstrate the synthesis of motor fuels from bioethanol. The conversion mechanism included the dehydration of ethanol with isomerization and ring closure in the hydrocarbon fragments or hydrogenation. It was observed during the study that the conversion of ethanol can be affected by process parameters like temperature, pressure, and raw material feed rate. It was also found that the conversion of ethanol on catalysts based on high-silica ZSM-5 zeolites with silicate modulus Si:Al > 100 produced gas with ethylene and olefins. Conversion of ethanol on oxygen zeolites with Si:Al < 80 produced a liquid product as a mixture of aromatic, saturated, and olefinic hydrocarbons. Catalytic conversion of ethanol by biomass fermentation can be used as an alternative for oil refining and to reduce the carbon dioxide emission.

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JO - Chemistry and Technology of Fuels and Oils (English translation of Khimiya i Tekhnologiya Topliv i Masel)

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10.1007/s10553-009-0077-y