Synthesis of highly deactivated polyhalogenated aromatic compounds

Vasily Igorevich Sobolev, Sergey Ivlev, Vladimir Shagalov, Roman Ostvald, Ivan Zherin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The barium fluorobromate(III) was obtained as the product of interaction between barium fluoride and bromine(III) trifluoride. The heat of formation of Ba(BrF4)2 was found by isothermal calorimetry method. By the TG/DT analysis the thermal stability of Ba(BrF4)2 was researched. It was found that this compound is mostly stable in the atmosphere or argon up to 250 °C. It was shown that bromine trifluoride and its derive compounds with alkali and alkali-earth metals fluorides can be applied like a highly-active brominating agent in case of production of various composite materials based on polyhalogenated aromatics.

Original languageEnglish
Title of host publicationKey Engineering Materials
PublisherTrans Tech Publications Ltd
Pages269-274
Number of pages6
Volume683
ISBN (Print)9783038357292
DOIs
Publication statusPublished - 2016
Event12th International Conference on Prospects of Fundamental Sciences Development, PFSD 2015 - Tomsk, Russian Federation
Duration: 21 Apr 201524 Apr 2015

Publication series

NameKey Engineering Materials
Volume683
ISSN (Print)10139826

Other

Other12th International Conference on Prospects of Fundamental Sciences Development, PFSD 2015
CountryRussian Federation
CityTomsk
Period21.4.1524.4.15

Keywords

  • Bromine trifluoride
  • Composite
  • Polymer
  • Reinforced
  • Synthesis
  • Thermal stability

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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  • Cite this

    Sobolev, V. I., Ivlev, S., Shagalov, V., Ostvald, R., & Zherin, I. (2016). Synthesis of highly deactivated polyhalogenated aromatic compounds. In Key Engineering Materials (Vol. 683, pp. 269-274). (Key Engineering Materials; Vol. 683). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.683.269