Synthesis of highly deactivated polyhalogenated aromatic compounds

Vasily Igorevich Sobolev, Sergey Ivlev, Vladimir Shagalov, Roman Ostvald, Ivan Zherin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The barium fluorobromate(III) was obtained as the product of interaction between barium fluoride and bromine(III) trifluoride. The heat of formation of Ba(BrF4)2 was found by isothermal calorimetry method. By the TG/DT analysis the thermal stability of Ba(BrF4)2 was researched. It was found that this compound is mostly stable in the atmosphere or argon up to 250 °C. It was shown that bromine trifluoride and its derive compounds with alkali and alkali-earth metals fluorides can be applied like a highly-active brominating agent in case of production of various composite materials based on polyhalogenated aromatics.

Original languageEnglish
Title of host publicationKey Engineering Materials
PublisherTrans Tech Publications Ltd
Pages269-274
Number of pages6
Volume683
ISBN (Print)9783038357292
DOIs
Publication statusPublished - 2016
Event12th International Conference on Prospects of Fundamental Sciences Development, PFSD 2015 - Tomsk, Russian Federation
Duration: 21 Apr 201524 Apr 2015

Publication series

NameKey Engineering Materials
Volume683
ISSN (Print)10139826

Other

Other12th International Conference on Prospects of Fundamental Sciences Development, PFSD 2015
CountryRussian Federation
CityTomsk
Period21.4.1524.4.15

Fingerprint

Aromatic compounds
Bromine
Alkalies
Barium
Argon
Calorimetry
Fluorides
Thermodynamic stability
Metals
Earth (planet)
Composite materials
Hot Temperature
bromine trifluoride
barium fluoride

Keywords

  • Bromine trifluoride
  • Composite
  • Polymer
  • Reinforced
  • Synthesis
  • Thermal stability

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Sobolev, V. I., Ivlev, S., Shagalov, V., Ostvald, R., & Zherin, I. (2016). Synthesis of highly deactivated polyhalogenated aromatic compounds. In Key Engineering Materials (Vol. 683, pp. 269-274). (Key Engineering Materials; Vol. 683). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.683.269

Synthesis of highly deactivated polyhalogenated aromatic compounds. / Sobolev, Vasily Igorevich; Ivlev, Sergey; Shagalov, Vladimir; Ostvald, Roman; Zherin, Ivan.

Key Engineering Materials. Vol. 683 Trans Tech Publications Ltd, 2016. p. 269-274 (Key Engineering Materials; Vol. 683).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sobolev, VI, Ivlev, S, Shagalov, V, Ostvald, R & Zherin, I 2016, Synthesis of highly deactivated polyhalogenated aromatic compounds. in Key Engineering Materials. vol. 683, Key Engineering Materials, vol. 683, Trans Tech Publications Ltd, pp. 269-274, 12th International Conference on Prospects of Fundamental Sciences Development, PFSD 2015, Tomsk, Russian Federation, 21.4.15. https://doi.org/10.4028/www.scientific.net/KEM.683.269
Sobolev VI, Ivlev S, Shagalov V, Ostvald R, Zherin I. Synthesis of highly deactivated polyhalogenated aromatic compounds. In Key Engineering Materials. Vol. 683. Trans Tech Publications Ltd. 2016. p. 269-274. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.683.269
Sobolev, Vasily Igorevich ; Ivlev, Sergey ; Shagalov, Vladimir ; Ostvald, Roman ; Zherin, Ivan. / Synthesis of highly deactivated polyhalogenated aromatic compounds. Key Engineering Materials. Vol. 683 Trans Tech Publications Ltd, 2016. pp. 269-274 (Key Engineering Materials).
@inproceedings{b880bec4ae394466b032992d6ee78857,
title = "Synthesis of highly deactivated polyhalogenated aromatic compounds",
abstract = "The barium fluorobromate(III) was obtained as the product of interaction between barium fluoride and bromine(III) trifluoride. The heat of formation of Ba(BrF4)2 was found by isothermal calorimetry method. By the TG/DT analysis the thermal stability of Ba(BrF4)2 was researched. It was found that this compound is mostly stable in the atmosphere or argon up to 250 °C. It was shown that bromine trifluoride and its derive compounds with alkali and alkali-earth metals fluorides can be applied like a highly-active brominating agent in case of production of various composite materials based on polyhalogenated aromatics.",
keywords = "Bromine trifluoride, Composite, Polymer, Reinforced, Synthesis, Thermal stability",
author = "Sobolev, {Vasily Igorevich} and Sergey Ivlev and Vladimir Shagalov and Roman Ostvald and Ivan Zherin",
year = "2016",
doi = "10.4028/www.scientific.net/KEM.683.269",
language = "English",
isbn = "9783038357292",
volume = "683",
series = "Key Engineering Materials",
publisher = "Trans Tech Publications Ltd",
pages = "269--274",
booktitle = "Key Engineering Materials",

}

TY - GEN

T1 - Synthesis of highly deactivated polyhalogenated aromatic compounds

AU - Sobolev, Vasily Igorevich

AU - Ivlev, Sergey

AU - Shagalov, Vladimir

AU - Ostvald, Roman

AU - Zherin, Ivan

PY - 2016

Y1 - 2016

N2 - The barium fluorobromate(III) was obtained as the product of interaction between barium fluoride and bromine(III) trifluoride. The heat of formation of Ba(BrF4)2 was found by isothermal calorimetry method. By the TG/DT analysis the thermal stability of Ba(BrF4)2 was researched. It was found that this compound is mostly stable in the atmosphere or argon up to 250 °C. It was shown that bromine trifluoride and its derive compounds with alkali and alkali-earth metals fluorides can be applied like a highly-active brominating agent in case of production of various composite materials based on polyhalogenated aromatics.

AB - The barium fluorobromate(III) was obtained as the product of interaction between barium fluoride and bromine(III) trifluoride. The heat of formation of Ba(BrF4)2 was found by isothermal calorimetry method. By the TG/DT analysis the thermal stability of Ba(BrF4)2 was researched. It was found that this compound is mostly stable in the atmosphere or argon up to 250 °C. It was shown that bromine trifluoride and its derive compounds with alkali and alkali-earth metals fluorides can be applied like a highly-active brominating agent in case of production of various composite materials based on polyhalogenated aromatics.

KW - Bromine trifluoride

KW - Composite

KW - Polymer

KW - Reinforced

KW - Synthesis

KW - Thermal stability

UR - http://www.scopus.com/inward/record.url?scp=84959114949&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84959114949&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/KEM.683.269

DO - 10.4028/www.scientific.net/KEM.683.269

M3 - Conference contribution

AN - SCOPUS:84959114949

SN - 9783038357292

VL - 683

T3 - Key Engineering Materials

SP - 269

EP - 274

BT - Key Engineering Materials

PB - Trans Tech Publications Ltd

ER -