Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins

Alexander V. Nyuchev, Kirill V. Schegravin, Michail A. Lopatin, Valery V. Fokin, Irina P. Beletskaya, Alexey Yu Fedorov

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

Original languageEnglish
Pages (from-to)3239-3248
Number of pages10
JournalSynthesis (Germany)
Volume46
Issue number23
DOIs
Publication statusPublished - 3 Sep 2014
Externally publishedYes

Fingerprint

4-Hydroxycoumarins
Coumarins
Boron
Luminescence
Imaging techniques
boron difluoride
4-hydroxycoumarin

Keywords

  • acylation
  • carbohydrates
  • click chemistry
  • coumarin
  • fluorescence

ASJC Scopus subject areas

  • Organic Chemistry
  • Catalysis

Cite this

Nyuchev, A. V., Schegravin, K. V., Lopatin, M. A., Fokin, V. V., Beletskaya, I. P., & Fedorov, A. Y. (2014). Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins. Synthesis (Germany), 46(23), 3239-3248. https://doi.org/10.1055/s-0034-1379020

Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins. / Nyuchev, Alexander V.; Schegravin, Kirill V.; Lopatin, Michail A.; Fokin, Valery V.; Beletskaya, Irina P.; Fedorov, Alexey Yu.

In: Synthesis (Germany), Vol. 46, No. 23, 03.09.2014, p. 3239-3248.

Research output: Contribution to journal › Article

Nyuchev, AV, Schegravin, KV, Lopatin, MA, Fokin, VV, Beletskaya, IP & Fedorov, AY 2014, 'Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins', Synthesis (Germany), vol. 46, no. 23, pp. 3239-3248. https://doi.org/10.1055/s-0034-1379020
Nyuchev AV, Schegravin KV, Lopatin MA, Fokin VV, Beletskaya IP, Fedorov AY. Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins. Synthesis (Germany). 2014 Sep 3;46(23):3239-3248. https://doi.org/10.1055/s-0034-1379020
Nyuchev, Alexander V. ; Schegravin, Kirill V. ; Lopatin, Michail A. ; Fokin, Valery V. ; Beletskaya, Irina P. ; Fedorov, Alexey Yu. / Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins. In: Synthesis (Germany). 2014 ; Vol. 46, No. 23. pp. 3239-3248.
@article{eab9e26de06640f781d5daae4e892d40,
title = "Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins",
abstract = "A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.",
keywords = "acylation, carbohydrates, click chemistry, coumarin, fluorescence",
author = "Nyuchev, {Alexander V.} and Schegravin, {Kirill V.} and Lopatin, {Michail A.} and Fokin, {Valery V.} and Beletskaya, {Irina P.} and Fedorov, {Alexey Yu}",
year = "2014",
month = "9",
day = "3",
doi = "10.1055/s-0034-1379020",
language = "English",
volume = "46",
pages = "3239--3248",
journal = "Synthesis",
issn = "0039-7881",
publisher = "Georg Thieme Verlag",
number = "23",

}

TY - JOUR

T1 - Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins

AU - Nyuchev, Alexander V.

AU - Schegravin, Kirill V.

AU - Lopatin, Michail A.

AU - Fokin, Valery V.

AU - Beletskaya, Irina P.

AU - Fedorov, Alexey Yu

PY - 2014/9/3

Y1 - 2014/9/3

N2 - A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

AB - A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

KW - acylation

KW - carbohydrates

KW - click chemistry

KW - coumarin

KW - fluorescence

UR - http://www.scopus.com/inward/record.url?scp=84911381922&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84911381922&partnerID=8YFLogxK

U2 - 10.1055/s-0034-1379020

DO - 10.1055/s-0034-1379020

M3 - Article

VL - 46

SP - 3239

EP - 3248

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 23

ER -

Access to Document