Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins

Alexander V. Nyuchev, Kirill V. Schegravin, Michail A. Lopatin, Valery V. Fokin, Irina P. Beletskaya, Alexey Yu Fedorov

Research output: Contribution to journal › Article › peer-review

Abstract

A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

Original language	English
Pages (from-to)	3239-3248
Number of pages	10
Journal	Synthesis (Germany)
Volume	46
Issue number	23
DOIs	https://doi.org/10.1055/s-0034-1379020
Publication status	Published - 3 Sep 2014
Externally published	Yes

Keywords

acylation
carbohydrates
click chemistry
coumarin
fluorescence

ASJC Scopus subject areas

Organic Chemistry
Catalysis

Access to Document

10.1055/s-0034-1379020

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abstract = "A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.",

keywords = "acylation, carbohydrates, click chemistry, coumarin, fluorescence",

author = "Nyuchev, {Alexander V.} and Schegravin, {Kirill V.} and Lopatin, {Michail A.} and Fokin, {Valery V.} and Beletskaya, {Irina P.} and Fedorov, {Alexey Yu}",

year = "2014",

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T1 - Synthesis of fluorescent boron difluoride complexes of 3-acyl-4-hydroxy-coumarins

AU - Nyuchev, Alexander V.

AU - Schegravin, Kirill V.

AU - Lopatin, Michail A.

AU - Fokin, Valery V.

AU - Beletskaya, Irina P.

AU - Fedorov, Alexey Yu

PY - 2014/9/3

Y1 - 2014/9/3

N2 - A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

AB - A series of boron difluoride-3-acyl-4-hydroxycoumarin complexes were synthesized in good yields in three steps starting from 4-hydroxycoumarins. The boron complexes showed strong luminescence in the green-yellow region and are compatible with surface imaging applications.

KW - acylation

KW - carbohydrates

KW - click chemistry

KW - coumarin

KW - fluorescence

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