Abstract
Pseudocyclic 2-benzimidazolyl-substituted diaryliodonium salts were obtained by the reaction of the corresponding [hydroxy(tosyloxy)iodo]arenes with arenes in the presence of trifluoromethanesulfonic acid. X-ray structural analysis of these iodonium salts confirmed their pseudocyclic structure with a short (2.57-2.58 Å) noncovalent I···N interaction. Treatment of 2-benzimidazolyl-substituted diaryliodonium triflates with a base afforded novel five-membered iodine-nitrogen heterocycles.
| Original language | English |
|---|---|
| Pages (from-to) | 12056-12070 |
| Number of pages | 15 |
| Journal | Journal of Organic Chemistry |
| Volume | 83 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 5 Oct 2018 |
ASJC Scopus subject areas
- Organic Chemistry
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Vlasenko, Y. A., Postnikov, P. S., Trusova, M. E., Shafir, A., Zhdankin, V. V., Yoshimura, A., & Yusubov, M. S. (2018). Synthesis of Five-Membered Iodine-Nitrogen Heterocycles from Benzimidazole-Based Iodonium Salts. Journal of Organic Chemistry, 83(19), 12056-12070. https://doi.org/10.1021/acs.joc.8b01995