Abstract
Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.
Original language | English |
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Pages (from-to) | 1953-1964 |
Number of pages | 12 |
Journal | Russian Chemical Bulletin |
Volume | 69 |
Issue number | 10 |
DOIs | |
Publication status | Published - 1 Oct 2020 |
Externally published | Yes |
Keywords
- adamantane
- coordination compounds
- copper
- pyrazole
- triazole
- X-ray diffraction
- zinc
ASJC Scopus subject areas
- Chemistry(all)