Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds

Abstract

Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.

Original language	English
Pages (from-to)	1953-1964
Number of pages	12
Journal	Russian Chemical Bulletin
Volume	69
Issue number	10
DOIs	https://doi.org/10.1007/s11172-020-2985-2
Publication status	Published - 1 Oct 2020
Externally published	Yes

Keywords

adamantane
coordination compounds
copper
pyrazole
triazole
X-ray diffraction
zinc

ASJC Scopus subject areas

Chemistry(all)

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10.1007/s11172-020-2985-2

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title = "Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds",

abstract = "Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.",

keywords = "adamantane, coordination compounds, copper, pyrazole, triazole, X-ray diffraction, zinc",

author = "Pavlov, {D. I.} and Sukhikh, {T. S.} and Potapov, {A. S.}",

year = "2020",

month = oct,

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doi = "10.1007/s11172-020-2985-2",

language = "English",

volume = "69",

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journal = "Russian Chemical Bulletin",

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T1 - Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds

AU - Pavlov, D. I.

AU - Sukhikh, T. S.

AU - Potapov, A. S.

PY - 2020/10/1

Y1 - 2020/10/1

N2 - Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.

AB - Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.

KW - adamantane

KW - coordination compounds

KW - copper

KW - pyrazole

KW - triazole

KW - X-ray diffraction

KW - zinc

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DO - 10.1007/s11172-020-2985-2

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EP - 1964

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