Abstract
1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.
| Original language | English |
|---|---|
| Pages (from-to) | 1346-1350 |
| Number of pages | 5 |
| Journal | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
| Volume | 29 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1 Aug 1980 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Synthesis of acetylenyl-N-methylpyrroles. / Vasilevskii, S. F.; Sundukova, T. A.; Shvartsberg, M. S.; Kotlyarevskii, I. L.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 29, No. 8, 01.08.1980, p. 1346-1350.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis of acetylenyl-N-methylpyrroles
AU - Vasilevskii, S. F.
AU - Sundukova, T. A.
AU - Shvartsberg, M. S.
AU - Kotlyarevskii, I. L.
PY - 1980/8/1
Y1 - 1980/8/1
N2 - 1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.
AB - 1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.
UR - http://www.scopus.com/inward/record.url?scp=0142129793&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0142129793&partnerID=8YFLogxK
U2 - 10.1007/BF00950586
DO - 10.1007/BF00950586
M3 - Article
VL - 29
SP - 1346
EP - 1350
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 0568-5230
IS - 8
ER -