Synthesis of acetylenyl-N-methylpyrroles

S. F. Vasilevskii, T. A. Sundukova, M. S. Shvartsberg, I. L. Kotlyarevskii

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Abstract

1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.

Original language	English
Pages (from-to)	1346-1350
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	29
Issue number	8
DOIs	https://doi.org/10.1007/BF00950586
Publication status	Published - 1 Aug 1980
Externally published	Yes

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Chemistry(all)

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Vasilevskii, S. F., Sundukova, T. A., Shvartsberg, M. S., & Kotlyarevskii, I. L. (1980). Synthesis of acetylenyl-N-methylpyrroles. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 29(8), 1346-1350. https://doi.org/10.1007/BF00950586

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AU - Vasilevskii, S. F.

AU - Sundukova, T. A.

AU - Shvartsberg, M. S.

AU - Kotlyarevskii, I. L.

PY - 1980/8/1

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N2 - 1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.

AB - 1. Iodine atoms in any position of the pyrrole ring are capable of being replaced by acetylenic groups under the conditions of palladium complex and copper catalysis. We accomplished the acetylenic condensation of a number of α- and β-iodopyrroles. 2. The alkaline cleavage of the thus-synthesized tertiary pyrrolylacetylenic alcohols leads to ethynylpyrroles.

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Access to Document

10.1007/BF00950586