Synthesis of a novel red phosphor K2xBa1-xTiF6:Mn4+ and its enhanced luminescence performance, thermal stability and waterproofness

Shuangqiang Fang, Tao Han, Tianchun Lang, Yang Zhong, Bitao Liu, Shixu Cao, Lingling Peng, Alexey N. Yakovlev, Vladimir I. Korepanov

Research output: Contribution to journalArticle

Abstract

Investigation of efficient red phosphors is highly desired for the development of novel warm white light emitting diodes. In this paper, through a facile method, we first introduce K+ to replace Ba2+ to synthesize a novel K2xBa1-xTiF6:Mn4+ solid solution phosphor with high luminous efficiency, high thermal stability and good waterproofness. Significantly, compared with two best luminescence performance samples (BaTiF6:0.006Mn4+ and K0.070Ba0.965TiF6:0.018Mn4+), the luminescence intensity of K0.070Ba0.965TiF6:0.018Mn4+ is increased by 6 times, the quantum efficiency is improved from 40% to 75% and the activation energy of thermal quenching is improved to 0.940 eV from 0.628 eV. Remarkably, the waterproofness is improved by 45% than traditional red phosphor K2TiF6:Mn4+ after being immersed in water for 150 min. Moreover, a high-performance WLED with low correlated color temperature (CCT = 3930 K), high color rendering index (Ra = 90.3) and luminous efficacy of 105 lm/W is achieved by employing blue-emitting GaN chip, yellow-emitting YAG:Ce3+ phosphor and red-emitting K0.070Ba0.965TiF6:Mn4+ phosphor. These results reveal that introduced suitable cation may have a positive effect on luminescent properties of Mn4+ activated fluoride phosphors, which is a helpful tool for their performance improvement, and K0.070Ba0.965TiF6:Mn4+ presents a good luminescent property and may be a potential candidate for high-performance warm WLED.

Original languageEnglish
Article number151697
JournalJournal of Alloys and Compounds
Volume808
DOIs
Publication statusPublished - 5 Nov 2019

Fingerprint

Phosphors
Luminescence
Thermodynamic stability
Color
Quantum efficiency
Fluorides
Light emitting diodes
Cations
Quenching
Solid solutions
Activation energy
Positive ions
Water
Temperature

Keywords

  • Luminescence performance
  • Mn
  • Phosphor
  • Thermal stability
  • Waterproofness

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Synthesis of a novel red phosphor K2xBa1-xTiF6:Mn4+ and its enhanced luminescence performance, thermal stability and waterproofness. / Fang, Shuangqiang; Han, Tao; Lang, Tianchun; Zhong, Yang; Liu, Bitao; Cao, Shixu; Peng, Lingling; Yakovlev, Alexey N.; Korepanov, Vladimir I.

In: Journal of Alloys and Compounds, Vol. 808, 151697, 05.11.2019.

Research output: Contribution to journalArticle

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abstract = "Investigation of efficient red phosphors is highly desired for the development of novel warm white light emitting diodes. In this paper, through a facile method, we first introduce K+ to replace Ba2+ to synthesize a novel K2xBa1-xTiF6:Mn4+ solid solution phosphor with high luminous efficiency, high thermal stability and good waterproofness. Significantly, compared with two best luminescence performance samples (BaTiF6:0.006Mn4+ and K0.070Ba0.965TiF6:0.018Mn4+), the luminescence intensity of K0.070Ba0.965TiF6:0.018Mn4+ is increased by 6 times, the quantum efficiency is improved from 40{\%} to 75{\%} and the activation energy of thermal quenching is improved to 0.940 eV from 0.628 eV. Remarkably, the waterproofness is improved by 45{\%} than traditional red phosphor K2TiF6:Mn4+ after being immersed in water for 150 min. Moreover, a high-performance WLED with low correlated color temperature (CCT = 3930 K), high color rendering index (Ra = 90.3) and luminous efficacy of 105 lm/W is achieved by employing blue-emitting GaN chip, yellow-emitting YAG:Ce3+ phosphor and red-emitting K0.070Ba0.965TiF6:Mn4+ phosphor. These results reveal that introduced suitable cation may have a positive effect on luminescent properties of Mn4+ activated fluoride phosphors, which is a helpful tool for their performance improvement, and K0.070Ba0.965TiF6:Mn4+ presents a good luminescent property and may be a potential candidate for high-performance warm WLED.",
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T1 - Synthesis of a novel red phosphor K2xBa1-xTiF6:Mn4+ and its enhanced luminescence performance, thermal stability and waterproofness

AU - Fang, Shuangqiang

AU - Han, Tao

AU - Lang, Tianchun

AU - Zhong, Yang

AU - Liu, Bitao

AU - Cao, Shixu

AU - Peng, Lingling

AU - Yakovlev, Alexey N.

AU - Korepanov, Vladimir I.

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N2 - Investigation of efficient red phosphors is highly desired for the development of novel warm white light emitting diodes. In this paper, through a facile method, we first introduce K+ to replace Ba2+ to synthesize a novel K2xBa1-xTiF6:Mn4+ solid solution phosphor with high luminous efficiency, high thermal stability and good waterproofness. Significantly, compared with two best luminescence performance samples (BaTiF6:0.006Mn4+ and K0.070Ba0.965TiF6:0.018Mn4+), the luminescence intensity of K0.070Ba0.965TiF6:0.018Mn4+ is increased by 6 times, the quantum efficiency is improved from 40% to 75% and the activation energy of thermal quenching is improved to 0.940 eV from 0.628 eV. Remarkably, the waterproofness is improved by 45% than traditional red phosphor K2TiF6:Mn4+ after being immersed in water for 150 min. Moreover, a high-performance WLED with low correlated color temperature (CCT = 3930 K), high color rendering index (Ra = 90.3) and luminous efficacy of 105 lm/W is achieved by employing blue-emitting GaN chip, yellow-emitting YAG:Ce3+ phosphor and red-emitting K0.070Ba0.965TiF6:Mn4+ phosphor. These results reveal that introduced suitable cation may have a positive effect on luminescent properties of Mn4+ activated fluoride phosphors, which is a helpful tool for their performance improvement, and K0.070Ba0.965TiF6:Mn4+ presents a good luminescent property and may be a potential candidate for high-performance warm WLED.

AB - Investigation of efficient red phosphors is highly desired for the development of novel warm white light emitting diodes. In this paper, through a facile method, we first introduce K+ to replace Ba2+ to synthesize a novel K2xBa1-xTiF6:Mn4+ solid solution phosphor with high luminous efficiency, high thermal stability and good waterproofness. Significantly, compared with two best luminescence performance samples (BaTiF6:0.006Mn4+ and K0.070Ba0.965TiF6:0.018Mn4+), the luminescence intensity of K0.070Ba0.965TiF6:0.018Mn4+ is increased by 6 times, the quantum efficiency is improved from 40% to 75% and the activation energy of thermal quenching is improved to 0.940 eV from 0.628 eV. Remarkably, the waterproofness is improved by 45% than traditional red phosphor K2TiF6:Mn4+ after being immersed in water for 150 min. Moreover, a high-performance WLED with low correlated color temperature (CCT = 3930 K), high color rendering index (Ra = 90.3) and luminous efficacy of 105 lm/W is achieved by employing blue-emitting GaN chip, yellow-emitting YAG:Ce3+ phosphor and red-emitting K0.070Ba0.965TiF6:Mn4+ phosphor. These results reveal that introduced suitable cation may have a positive effect on luminescent properties of Mn4+ activated fluoride phosphors, which is a helpful tool for their performance improvement, and K0.070Ba0.965TiF6:Mn4+ presents a good luminescent property and may be a potential candidate for high-performance warm WLED.

KW - Luminescence performance

KW - Mn

KW - Phosphor

KW - Thermal stability

KW - Waterproofness

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