Synthesis, crystal structure and luminescent properties of 2D zinc coordination polymers based on bis(1,2,4-triazol-1-yl)methane and 1,3-bis(1,2,4-triazol-1-yl)propane

Evgeny Semitut, Taisiya Sukhikh, Evgeny Filatov, Alexey Ryadun, Andrei Potapov

The Kizhner Research Center

Research output: Contribution to journal › Article

Abstract

Two new two-dimensional zinc(II) coordination polymers containing 2,5- thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.

Original language	English
Article number	354
Journal	Crystals
Volume	7
Issue number	12
DOIs	https://doi.org/10.3390/cryst7120354
Publication status	Published - 1 Dec 2017

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Keywords

1,3-bis(1,2,4-triazol-1-yl)propane
2,5-thiophenedicarboxylic acid
Bis(1,2,4-triazol-1-yl)methane
Bitopic ligand
Coordination polymer
Crystal structure
Luminescence
Thermal analysis
Zinc

ASJC Scopus subject areas

Chemical Engineering(all)
Materials Science(all)
Condensed Matter Physics
Inorganic Chemistry

Cite this

Semitut, E., Sukhikh, T., Filatov, E., Ryadun, A., & Potapov, A. (2017). Synthesis, crystal structure and luminescent properties of 2D zinc coordination polymers based on bis(1,2,4-triazol-1-yl)methane and 1,3-bis(1,2,4-triazol-1-yl)propane. Crystals, 7(12), [354]. https://doi.org/10.3390/cryst7120354

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abstract = "Two new two-dimensional zinc(II) coordination polymers containing 2,5- thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.",

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author = "Evgeny Semitut and Taisiya Sukhikh and Evgeny Filatov and Alexey Ryadun and Andrei Potapov",

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T1 - Synthesis, crystal structure and luminescent properties of 2D zinc coordination polymers based on bis(1,2,4-triazol-1-yl)methane and 1,3-bis(1,2,4-triazol-1-yl)propane

AU - Semitut, Evgeny

AU - Sukhikh, Taisiya

AU - Filatov, Evgeny

AU - Ryadun, Alexey

AU - Potapov, Andrei

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Two new two-dimensional zinc(II) coordination polymers containing 2,5- thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.

AB - Two new two-dimensional zinc(II) coordination polymers containing 2,5- thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.

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KW - Bis(1,2,4-triazol-1-yl)methane

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KW - Coordination polymer

KW - Crystal structure

KW - Luminescence

KW - Thermal analysis

KW - Zinc

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Access to Document

10.3390/cryst7120354