Synthesis, crystal structure and luminescent properties of 2D zinc coordination polymers based on bis(1,2,4-triazol-1-yl)methane and 1,3-bis(1,2,4-triazol-1-yl)propane

Evgeny Semitut, Taisiya Sukhikh, Evgeny Filatov, Alexey Ryadun, Andrei Potapov

Research output: Contribution to journalArticle

Abstract

Two new two-dimensional zinc(II) coordination polymers containing 2,5- thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed.

Original languageEnglish
Article number354
JournalCrystals
Volume7
Issue number12
DOIs
Publication statusPublished - 1 Dec 2017

Fingerprint

Propane
Methane
coordination polymers
propane
Zinc
Polymers
methane
zinc
Crystal structure
crystal structure
synthesis
X ray diffraction analysis
Thermoanalysis
Infrared spectroscopy
thermal analysis
Ligands
Powders
ligands
Chemical analysis
diffraction

Keywords

  • 1,3-bis(1,2,4-triazol-1-yl)propane
  • 2,5-thiophenedicarboxylic acid
  • Bis(1,2,4-triazol-1-yl)methane
  • Bitopic ligand
  • Coordination polymer
  • Crystal structure
  • Luminescence
  • Thermal analysis
  • Zinc

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

Synthesis, crystal structure and luminescent properties of 2D zinc coordination polymers based on bis(1,2,4-triazol-1-yl)methane and 1,3-bis(1,2,4-triazol-1-yl)propane. / Semitut, Evgeny; Sukhikh, Taisiya; Filatov, Evgeny; Ryadun, Alexey; Potapov, Andrei.

In: Crystals, Vol. 7, No. 12, 354, 01.12.2017.

Research output: Contribution to journalArticle

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