Abstract
This paper discusses synthesis condition effect on the structure and morphology of ZrW2O8 using thermal decomposition of precursor ZrW2O7(OH,Cl)2·2H2O prepared by hydrothermal method. It was observed that for hydrothermal precursor synthesis the optimal concentration of hydrochloric acid in the reaction mixture was about 2.3 M and sintering time amounted to 36 hours. The precursor morphology was in the form of needle-like particles and loose irregular shape agglomerates. The pure nanoscale ZrW2O8 powder was obtained by precursor heating at 570°C for 1 hour and has needle-like particles with an intrinsic block structure. The average block size was 50 nm. The average transverse size was less than 1 μm, the longitudinal particle size varied from 500 to 5000 nm.
| Original language | English |
|---|---|
| Title of host publication | Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016: Proceedings of the International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016 |
| Publisher | American Institute of Physics Inc. |
| Volume | 1783 |
| ISBN (Electronic) | 9780735414457 |
| DOIs | |
| Publication status | Published - 10 Nov 2016 |
| Event | International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016 - Tomsk, Russian Federation Duration: 19 Sep 2016 → 23 Sep 2016 |
Conference
| Conference | International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 19.9.16 → 23.9.16 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
Synthesis conditions and sintered ZrW2O8 structure. / Dedova, Elena S.; Gubanov, Alexander I.; Filatov, Eugeny Y.; Kardash, Tatyana Y.; Kul'kov, Sergey Nikolaevich.
Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016: Proceedings of the International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016. Vol. 1783 American Institute of Physics Inc., 2016. 020036.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Synthesis conditions and sintered ZrW2O8 structure
AU - Dedova, Elena S.
AU - Gubanov, Alexander I.
AU - Filatov, Eugeny Y.
AU - Kardash, Tatyana Y.
AU - Kul'kov, Sergey Nikolaevich
PY - 2016/11/10
Y1 - 2016/11/10
N2 - This paper discusses synthesis condition effect on the structure and morphology of ZrW2O8 using thermal decomposition of precursor ZrW2O7(OH,Cl)2·2H2O prepared by hydrothermal method. It was observed that for hydrothermal precursor synthesis the optimal concentration of hydrochloric acid in the reaction mixture was about 2.3 M and sintering time amounted to 36 hours. The precursor morphology was in the form of needle-like particles and loose irregular shape agglomerates. The pure nanoscale ZrW2O8 powder was obtained by precursor heating at 570°C for 1 hour and has needle-like particles with an intrinsic block structure. The average block size was 50 nm. The average transverse size was less than 1 μm, the longitudinal particle size varied from 500 to 5000 nm.
AB - This paper discusses synthesis condition effect on the structure and morphology of ZrW2O8 using thermal decomposition of precursor ZrW2O7(OH,Cl)2·2H2O prepared by hydrothermal method. It was observed that for hydrothermal precursor synthesis the optimal concentration of hydrochloric acid in the reaction mixture was about 2.3 M and sintering time amounted to 36 hours. The precursor morphology was in the form of needle-like particles and loose irregular shape agglomerates. The pure nanoscale ZrW2O8 powder was obtained by precursor heating at 570°C for 1 hour and has needle-like particles with an intrinsic block structure. The average block size was 50 nm. The average transverse size was less than 1 μm, the longitudinal particle size varied from 500 to 5000 nm.
UR - http://www.scopus.com/inward/record.url?scp=85005943167&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85005943167&partnerID=8YFLogxK
U2 - 10.1063/1.4966329
DO - 10.1063/1.4966329
M3 - Conference contribution
AN - SCOPUS:85005943167
VL - 1783
BT - Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016: Proceedings of the International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016
PB - American Institute of Physics Inc.
ER -