Synthesis and structure of Pb(Bipy)2(6-B10H13CN)

Abstract

The lead complex with the [6-B₁₀H₁₃CN]² - anion and 2,2′-bipyridine is synthesized and characterized. According to the X-ray diffraction data, the crystals are triclinic, a = 9.547(3), b = 13.003(4), c = 13.319(3) Å, α = 79.65(2)°, β = 73.05(2)°, γ = 75.94(2)°, V = 1523.7(7) Å³, Z = 2, space group P1. The lead atom is coordinated by two chelating bipyridine ligands. The Pb-B distances are in the range 3.46-3.51 Å.

Original language	English
Pages (from-to)	110-115
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	22
Issue number	2
Publication status	Published - Feb 1996
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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@article{551591b75dbc4348bb72d959401e060b,

title = "Synthesis and structure of Pb(Bipy)2(6-B10H13CN)",

abstract = "The lead complex with the [6-B10H13CN]2 - anion and 2,2′-bipyridine is synthesized and characterized. According to the X-ray diffraction data, the crystals are triclinic, a = 9.547(3), b = 13.003(4), c = 13.319(3) {\AA}, α = 79.65(2)°, β = 73.05(2)°, γ = 75.94(2)°, V = 1523.7(7) {\AA}3, Z = 2, space group P1. The lead atom is coordinated by two chelating bipyridine ligands. The Pb-B distances are in the range 3.46-3.51 {\AA}.",

author = "Orlova, {A. M.} and Sivaev, {I. B.} and Lagun, {V. L.} and Katser, {S. B.} and Solntsev, {K. A.} and Kuznetsov, {N. T.}",

year = "1996",

month = feb,

language = "English",

volume = "22",

pages = "110--115",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

TY - JOUR

T1 - Synthesis and structure of Pb(Bipy)2(6-B10H13CN)

AU - Orlova, A. M.

AU - Sivaev, I. B.

AU - Lagun, V. L.

AU - Katser, S. B.

AU - Solntsev, K. A.

AU - Kuznetsov, N. T.

PY - 1996/2

Y1 - 1996/2

N2 - The lead complex with the [6-B10H13CN]2 - anion and 2,2′-bipyridine is synthesized and characterized. According to the X-ray diffraction data, the crystals are triclinic, a = 9.547(3), b = 13.003(4), c = 13.319(3) Å, α = 79.65(2)°, β = 73.05(2)°, γ = 75.94(2)°, V = 1523.7(7) Å3, Z = 2, space group P1. The lead atom is coordinated by two chelating bipyridine ligands. The Pb-B distances are in the range 3.46-3.51 Å.

AB - The lead complex with the [6-B10H13CN]2 - anion and 2,2′-bipyridine is synthesized and characterized. According to the X-ray diffraction data, the crystals are triclinic, a = 9.547(3), b = 13.003(4), c = 13.319(3) Å, α = 79.65(2)°, β = 73.05(2)°, γ = 75.94(2)°, V = 1523.7(7) Å3, Z = 2, space group P1. The lead atom is coordinated by two chelating bipyridine ligands. The Pb-B distances are in the range 3.46-3.51 Å.

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UR - http://www.scopus.com/inward/citedby.url?scp=27644485629&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:27644485629

VL - 22

SP - 110

EP - 115

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

Synthesis and structure of Pb(Bipy)₂(6-B₁₀H₁₃CN)

Abstract

ASJC Scopus subject areas

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