Synthesis and structure of Pb(Bipy)2(6-B10H13CN)

A. M. Orlova, I. B. Sivaev, V. L. Lagun, S. B. Katser, K. A. Solntsev, N. T. Kuznetsov

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1 Citation (Scopus)

Abstract

The lead complex with the [6-B10H13CN]2 - anion and 2,2′-bipyridine is synthesized and characterized. According to the X-ray diffraction data, the crystals are triclinic, a = 9.547(3), b = 13.003(4), c = 13.319(3) Å, α = 79.65(2)°, β = 73.05(2)°, γ = 75.94(2)°, V = 1523.7(7) Å3, Z = 2, space group P1. The lead atom is coordinated by two chelating bipyridine ligands. The Pb-B distances are in the range 3.46-3.51 Å.

Original languageEnglish
Pages (from-to)110-115
Number of pages6
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume22
Issue number2
Publication statusPublished - Feb 1996
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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