Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes

Neil Grimster, Li Zhang, Valery V. Fokin

Research output: Contribution to journal › Article

Abstract

(Figure Presented) Highly reactive rhodium(II) N-trifluoromethylsulfonyl azavinyl carbenes are formed in situ from NH-1,2,3-triazoles, triflic anhydride, and rhodium carboxylates. They rapidly and selectively react with olefins, providing cyclopropane carboxaldehydes and 2,3-dihydropyrroles in generally excellent yields and high enantio- and diastereoselectivity.

Original language	English
Pages (from-to)	2510-2511
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	8
DOIs	https://doi.org/10.1021/ja910187s
Publication status	Published - 24 Feb 2010
Externally published	Yes

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ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

Cite this

Grimster, N., Zhang, L., & Fokin, V. V. (2010). Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes. Journal of the American Chemical Society, 132(8), 2510-2511. https://doi.org/10.1021/ja910187s

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10.1021/ja910187s