Synthesis and reactions of ethynylbenzocrown ethers

Svetlana V. Klyatskaya, Eugene V. Tretyakov, Sergei F. Vasilevsky

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of 4′-iodobenzo-15-crown-5 and -18-crown-6 ethers with 2-methyl-3-butyn-2-ol and trimethylsilylacetylene followed by treatment of the reaction products with alkali yields ethynylbenzocrown ethers; chemical transformations such as cross- and homo-coupling and Cadiot-Chodkiewicz and Mannich reaction of the ethynyl derivatives have been carried out.

Original language	English
Pages (from-to)	201-202
Number of pages	2
Journal	Mendeleev Communications
Volume	8
Issue number	5
Publication status	Published - 1 Jan 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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AB - The interaction of 4′-iodobenzo-15-crown-5 and -18-crown-6 ethers with 2-methyl-3-butyn-2-ol and trimethylsilylacetylene followed by treatment of the reaction products with alkali yields ethynylbenzocrown ethers; chemical transformations such as cross- and homo-coupling and Cadiot-Chodkiewicz and Mannich reaction of the ethynyl derivatives have been carried out.

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