Synthesis and fluorescent behaviour of 2-aryl-4,5-dihydro-1H-1,2,4-triazoles

Alexandra I. Eliseeva, Olga O. Nesterenko, Pavel A. Slepukhin, Enrico Benassi, Nataliya P. Belskaya

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5 Citations (Scopus)

Abstract

A series of new 4,5-dihydro-1H-1,2,4-triazoles was synthesized from amidrazones and acetylenedicarboxylic acid esters in the presence of pyridine in toluene. The synthesized compounds were characterized by 1H, 13C NMR, FT-IR spectral analyses and XRD data. Optical studies revealed that most of the compounds reported here exhibited emission of blue or greenyellow light upon irradiation in acetone and showed Stokes shifts in the region of 70-96 nm and quantum yields of up to 45%. The interpretation of the experimental findings was supported by state-of-the-art quantum mechanical calculations.

Original languageEnglish
Pages (from-to)86-100
Number of pages15
JournalJournal of Organic Chemistry
Volume82
Issue number1
DOIs
Publication statusPublished - 1 Jan 2017
Externally publishedYes

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ASJC Scopus subject areas

  • Organic Chemistry

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