Synthesis and characterization of transition metal complexes of 1,2-bis(3,5-dimethylpyrazol-1-yl)-1,2-ethanediol

Galyna A. Anosova, Vladislava V. Matveevskaya, Nurgul A. Pirmanova, Andrei S. Potapov

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Copper(II), nickel(II) and vanadyl complexes of 1,2-bis(3,5-dimethylpyrazol-1-yl)-1,2-ethanediol were prepared by the reaction of transition metal salts (chloride, acetate, sulfate) with the ligand in ethanol solution. The composition of the complexes was confirmed by elemental analysis and molar conductivity measurements. The coordination modes of the ligand and counter-ions were established from IR spectra and DFT calculations.

Original languageEnglish
Title of host publicationHigh Technology
Subtitle of host publicationResearch and Applications, 2015
PublisherTrans Tech Publications Ltd
Pages754-758
Number of pages5
Volume685
ISBN (Print)9783038357087
DOIs
Publication statusPublished - 2016
Event4th International Conference for Young Scientists High Technology: Research and Applications, HTRA 2015 - Tomsk, Russian Federation
Duration: 21 Apr 201524 Apr 2015

Publication series

NameKey Engineering Materials
Volume685
ISSN (Print)1013-9826

Conference

Conference4th International Conference for Young Scientists High Technology: Research and Applications, HTRA 2015
CountryRussian Federation
CityTomsk
Period21.4.1524.4.15

Keywords

  • Bis(pyrazol-1-yl)ethane
  • Complexes
  • Copper
  • Nickel
  • Scorpionate ligands
  • Vanadium

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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