Abstract
The tandem synthesis of 1,1′,1″-[mesityltris(methylene)tris(3-R-1H-imidazolium)] bromides (3a–f; R=methyl, isopropyl, vinyl, allyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl) and corresponding tris-selones 4a–f starting from tris(bromomethyl)mesitylene was investigated. The compounds were characterized by 1H, 13C, DEPT-135, HSQC, and HMBC NMR spectroscopy; IR spectroscopy; and elemental analysis. The unprecedented crystalline structures of the sterically hindered and synthetically challenging tris-selones possessing different geometrical orientations (with the exception of 4 f) were further corroborated by single-crystal X-ray diffraction analysis. Comparative UV/Vis analysis of 4a–f was also demonstrated.
| Original language | English |
|---|---|
| Journal | ChemistryOpen |
| Volume | 6 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1 Jan 2017 |
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Keywords
- Crystallinity
- NMR spectroscopy
- Selenium
- Structure elucidation
- X-ray diffraction
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Synthesis and characterization of sterically congested mesityltris(imidazolium) salts and the corresponding highly crystalline tris-selone derivatives. / Nath, Ipsita; Chakraborty, Jeet; Verpoort, Francis.
In: ChemistryOpen, Vol. 6, No. 5, 01.01.2017.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and characterization of sterically congested mesityltris(imidazolium) salts and the corresponding highly crystalline tris-selone derivatives
AU - Nath, Ipsita
AU - Chakraborty, Jeet
AU - Verpoort, Francis
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The tandem synthesis of 1,1′,1″-[mesityltris(methylene)tris(3-R-1H-imidazolium)] bromides (3a–f; R=methyl, isopropyl, vinyl, allyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl) and corresponding tris-selones 4a–f starting from tris(bromomethyl)mesitylene was investigated. The compounds were characterized by 1H, 13C, DEPT-135, HSQC, and HMBC NMR spectroscopy; IR spectroscopy; and elemental analysis. The unprecedented crystalline structures of the sterically hindered and synthetically challenging tris-selones possessing different geometrical orientations (with the exception of 4 f) were further corroborated by single-crystal X-ray diffraction analysis. Comparative UV/Vis analysis of 4a–f was also demonstrated.
AB - The tandem synthesis of 1,1′,1″-[mesityltris(methylene)tris(3-R-1H-imidazolium)] bromides (3a–f; R=methyl, isopropyl, vinyl, allyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl) and corresponding tris-selones 4a–f starting from tris(bromomethyl)mesitylene was investigated. The compounds were characterized by 1H, 13C, DEPT-135, HSQC, and HMBC NMR spectroscopy; IR spectroscopy; and elemental analysis. The unprecedented crystalline structures of the sterically hindered and synthetically challenging tris-selones possessing different geometrical orientations (with the exception of 4 f) were further corroborated by single-crystal X-ray diffraction analysis. Comparative UV/Vis analysis of 4a–f was also demonstrated.
KW - Crystallinity
KW - NMR spectroscopy
KW - Selenium
KW - Structure elucidation
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85032807744&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85032807744&partnerID=8YFLogxK
U2 - 10.1002/open.201700076
DO - 10.1002/open.201700076
M3 - Article
AN - SCOPUS:85032807744
VL - 6
JO - ChemistryOpen
JF - ChemistryOpen
SN - 2191-1363
IS - 5
ER -