Synthesis and characterization of barium hexafluoridoosmates

Sergei I. Ivlev, Antti J. Karttunen, Magnus R. Buchner, Matthias Conrad, Roman V. Ostvald, Florian Kraus

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)◦, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R3 with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2·3BrF3, Ba(OsF6)2·HF, Ba(OsF6)2·6H2O from the respective solvents, and Ba(OsF6)2.

Original languageEnglish
Article number11
JournalCrystals
Volume8
Issue number1
DOIs
Publication statusPublished - 1 Jan 2018

Fingerprint

Hydrofluoric Acid
Barium
Powders
Nuclear magnetic resonance spectroscopy
barium
Infrared spectroscopy
Diffraction
Single crystals
X rays
Hydrogen
hydrofluoric acid
synthesis
cells
spectroscopy
nuclear magnetic resonance
single crystals
diffraction
crystals
x rays

Keywords

  • Bromine trifluoride
  • Crystal structure
  • Fluorides
  • Osmium

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

Ivlev, S. I., Karttunen, A. J., Buchner, M. R., Conrad, M., Ostvald, R. V., & Kraus, F. (2018). Synthesis and characterization of barium hexafluoridoosmates. Crystals, 8(1), [11]. https://doi.org/10.3390/cryst8010011

Synthesis and characterization of barium hexafluoridoosmates. / Ivlev, Sergei I.; Karttunen, Antti J.; Buchner, Magnus R.; Conrad, Matthias; Ostvald, Roman V.; Kraus, Florian.

In: Crystals, Vol. 8, No. 1, 11, 01.01.2018.

Research output: Contribution to journal › Article

Ivlev, SI, Karttunen, AJ, Buchner, MR, Conrad, M, Ostvald, RV & Kraus, F 2018, 'Synthesis and characterization of barium hexafluoridoosmates', Crystals, vol. 8, no. 1, 11. https://doi.org/10.3390/cryst8010011
Ivlev SI, Karttunen AJ, Buchner MR, Conrad M, Ostvald RV, Kraus F. Synthesis and characterization of barium hexafluoridoosmates. Crystals. 2018 Jan 1;8(1). 11. https://doi.org/10.3390/cryst8010011
Ivlev, Sergei I. ; Karttunen, Antti J. ; Buchner, Magnus R. ; Conrad, Matthias ; Ostvald, Roman V. ; Kraus, Florian. / Synthesis and characterization of barium hexafluoridoosmates. In: Crystals. 2018 ; Vol. 8, No. 1.
@article{ab32d94a7e8d4bd59dbd916b0eb14e80,
title = "Synthesis and characterization of barium hexafluoridoosmates",
abstract = "Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) {\AA}, β = 115.195(5)◦, V = 930.42(12) {\AA}3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R3 with the cell parameters a = 7.3286(10), c = 7.2658(15) {\AA}, V = 337.95(12) {\AA}3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2·3BrF3, Ba(OsF6)2·HF, Ba(OsF6)2·6H2O from the respective solvents, and Ba(OsF6)2.",
keywords = "Bromine trifluoride, Crystal structure, Fluorides, Osmium",
author = "Ivlev, {Sergei I.} and Karttunen, {Antti J.} and Buchner, {Magnus R.} and Matthias Conrad and Ostvald, {Roman V.} and Florian Kraus",
year = "2018",
month = "1",
day = "1",
doi = "10.3390/cryst8010011",
language = "English",
volume = "8",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of barium hexafluoridoosmates

AU - Ivlev, Sergei I.

AU - Karttunen, Antti J.

AU - Buchner, Magnus R.

AU - Conrad, Matthias

AU - Ostvald, Roman V.

AU - Kraus, Florian

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)◦, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R3 with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2·3BrF3, Ba(OsF6)2·HF, Ba(OsF6)2·6H2O from the respective solvents, and Ba(OsF6)2.

AB - Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)◦, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R3 with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2·3BrF3, Ba(OsF6)2·HF, Ba(OsF6)2·6H2O from the respective solvents, and Ba(OsF6)2.

KW - Bromine trifluoride

KW - Crystal structure

KW - Fluorides

KW - Osmium

UR - http://www.scopus.com/inward/record.url?scp=85040521754&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85040521754&partnerID=8YFLogxK

U2 - 10.3390/cryst8010011

DO - 10.3390/cryst8010011

M3 - Article

VL - 8

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 1

M1 - 11

ER -

Access to Document