Synergistic performance of a sub-nanoscopic cobalt and imidazole grafted porous organic polymer for CO₂fixation to cyclic carbonates under ambient pressure without a co-catalyst

Jeet Chakraborty, Ipsita Nath, Shaoxian Song, Chih Ming Kao, Francis Verpoort

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

A facile, single-step development strategy of a sub-nanoscopic Lewis acidic Co and basic imidazole grafted porous organic polymer is reported. The synergistic activation of an epoxide and CO2 by the Lewis pairs present in the material manifested their rapid conversion to cyclic carbonates under ambient pressure with high yield, selectivity, and TOF.

Original language	English
Pages (from-to)	13916-13920
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	8
Issue number	28
DOIs	https://doi.org/10.1039/d0ta02821e
Publication status	Published - 28 Jul 2020

ASJC Scopus subject areas

Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

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10.1039/d0ta02821e

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Synergistic performance of a sub-nanoscopic cobalt and imidazole grafted porous organic polymer for CO₂fixation to cyclic carbonates under ambient pressure without a co-catalyst. / Chakraborty, Jeet; Nath, Ipsita; Song, Shaoxian; Kao, Chih Ming; Verpoort, Francis.

In: Journal of Materials Chemistry A, Vol. 8, No. 28, 28.07.2020, p. 13916-13920.

Research output: Contribution to journal › Article › peer-review

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abstract = "A facile, single-step development strategy of a sub-nanoscopic Lewis acidic Co and basic imidazole grafted porous organic polymer is reported. The synergistic activation of an epoxide and CO2 by the Lewis pairs present in the material manifested their rapid conversion to cyclic carbonates under ambient pressure with high yield, selectivity, and TOF.",

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AU - Song, Shaoxian

AU - Kao, Chih Ming

AU - Verpoort, Francis

PY - 2020/7/28

Y1 - 2020/7/28

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AB - A facile, single-step development strategy of a sub-nanoscopic Lewis acidic Co and basic imidazole grafted porous organic polymer is reported. The synergistic activation of an epoxide and CO2 by the Lewis pairs present in the material manifested their rapid conversion to cyclic carbonates under ambient pressure with high yield, selectivity, and TOF.

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Synergistic performance of a sub-nanoscopic cobalt and imidazole grafted porous organic polymer for CO2fixation to cyclic carbonates under ambient pressure without a co-catalyst

Abstract

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Synergistic performance of a sub-nanoscopic cobalt and imidazole grafted porous organic polymer for CO₂fixation to cyclic carbonates under ambient pressure without a co-catalyst