Superactive iodination reagent on a base of iodine chloride and silver sulfate

Vitold K. Chaikovski, Tatjana S. Kharlova, Victor D. Filimonov, Tamara A. Saryucheva

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.

Original languageEnglish
Pages (from-to)748-750
Number of pages3
JournalSynthesis
Issue number5
Publication statusPublished - 1999

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Aromatic compounds
Iodine
Sulfuric acid
Silver
Sulfates
sulfuric acid
iodine monochloride

Keywords

  • Aromatic compounds
  • Iodination
  • Iodine chloride

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Chaikovski, V. K., Kharlova, T. S., Filimonov, V. D., & Saryucheva, T. A. (1999). Superactive iodination reagent on a base of iodine chloride and silver sulfate. Synthesis, (5), 748-750.

Superactive iodination reagent on a base of iodine chloride and silver sulfate. / Chaikovski, Vitold K.; Kharlova, Tatjana S.; Filimonov, Victor D.; Saryucheva, Tamara A.

In: Synthesis, No. 5, 1999, p. 748-750.

Research output: Contribution to journalArticle

Chaikovski, VK, Kharlova, TS, Filimonov, VD & Saryucheva, TA 1999, 'Superactive iodination reagent on a base of iodine chloride and silver sulfate', Synthesis, no. 5, pp. 748-750.
Chaikovski, Vitold K. ; Kharlova, Tatjana S. ; Filimonov, Victor D. ; Saryucheva, Tamara A. / Superactive iodination reagent on a base of iodine chloride and silver sulfate. In: Synthesis. 1999 ; No. 5. pp. 748-750.
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