Abstract
After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.
| Original language | English |
|---|---|
| Pages (from-to) | 748-750 |
| Number of pages | 3 |
| Journal | Synthesis |
| Issue number | 5 |
| Publication status | Published - 1999 |
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Keywords
- Aromatic compounds
- Iodination
- Iodine chloride
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Superactive iodination reagent on a base of iodine chloride and silver sulfate. / Chaikovski, Vitold K.; Kharlova, Tatjana S.; Filimonov, Victor D.; Saryucheva, Tamara A.
In: Synthesis, No. 5, 1999, p. 748-750.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Superactive iodination reagent on a base of iodine chloride and silver sulfate
AU - Chaikovski, Vitold K.
AU - Kharlova, Tatjana S.
AU - Filimonov, Victor D.
AU - Saryucheva, Tamara A.
PY - 1999
Y1 - 1999
N2 - After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.
AB - After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.
KW - Aromatic compounds
KW - Iodination
KW - Iodine chloride
UR - http://www.scopus.com/inward/record.url?scp=0032958210&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032958210&partnerID=8YFLogxK
M3 - Article
SP - 748
EP - 750
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 5
ER -