Superactive iodination reagent on a base of iodine chloride and silver sulfate

Vitold K. Chaikovski, Tatjana S. Kharlova, Victor D. Filimonov, Tamara A. Saryucheva

The Kizhner Research Center

Research output: Contribution to journal › Article › peer-review

Abstract

After reaction of ICl and Ag₂SO₄ in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.

Original language	English
Pages (from-to)	748-750
Number of pages	3
Journal	Synthesis
Issue number	5
Publication status	Published - 1999

Keywords

Aromatic compounds
Iodination
Iodine chloride

ASJC Scopus subject areas

Organic Chemistry

Access to Document

Fingerprint Dive into the research topics of 'Superactive iodination reagent on a base of iodine chloride and silver sulfate'. Together they form a unique fingerprint.

Cite this

@article{49dd03f397b744fcaf78478bb06a651d,

title = "Superactive iodination reagent on a base of iodine chloride and silver sulfate",

abstract = "After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.",

keywords = "Aromatic compounds, Iodination, Iodine chloride",

author = "Chaikovski, {Vitold K.} and Kharlova, {Tatjana S.} and Filimonov, {Victor D.} and Saryucheva, {Tamara A.}",

year = "1999",

language = "English",

pages = "748--750",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "5",

}

TY - JOUR

T1 - Superactive iodination reagent on a base of iodine chloride and silver sulfate

AU - Chaikovski, Vitold K.

AU - Kharlova, Tatjana S.

AU - Filimonov, Victor D.

AU - Saryucheva, Tamara A.

PY - 1999

Y1 - 1999

N2 - After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.

AB - After reaction of ICl and Ag2SO4 in sulfuric acid and separation of resulting AgCl a stable solution is formed, containing very active forms of electrophilic iodine. This solution has a powerful iodination ability with respect to aromatic compounds. Deactivated arenes are iodinated easily and in mild conditions by action of this new reagent in generally good yields of the iodoarenes.

KW - Aromatic compounds

KW - Iodination

KW - Iodine chloride

UR - http://www.scopus.com/inward/record.url?scp=0032958210&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032958210&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032958210

SP - 748

EP - 750

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 5

ER -