The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.
ASJC Scopus subject areas
- Organic Chemistry