13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring

V. D. Filimonov, T. A. Filippova, V. P. Lopatinskii, M. M. Sukhoroslova

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The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.

Original languageEnglish
Pages (from-to)165-170
Number of pages6
JournalChemistry of Heterocyclic Compounds
Issue number2
Publication statusPublished - Feb 1984


ASJC Scopus subject areas

  • Organic Chemistry

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