13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring

V. D. Filimonov, T. A. Filippova, V. P. Lopatinskii, M. M. Sukhoroslova

Research output: Contribution to journalArticle

Abstract

The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.

Original languageEnglish
Pages (from-to)165-170
Number of pages6
JournalChemistry of Heterocyclic Compounds
Volume20
Issue number2
DOIs
Publication statusPublished - Feb 1984

Fingerprint

Chemical shift
Nuclear magnetic resonance
Electrons
Benzene
N-methylcarbazole
carbazole

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring. / Filimonov, V. D.; Filippova, T. A.; Lopatinskii, V. P.; Sukhoroslova, M. M.

In: Chemistry of Heterocyclic Compounds, Vol. 20, No. 2, 02.1984, p. 165-170.

Research output: Contribution to journalArticle

Filimonov, V. D. ; Filippova, T. A. ; Lopatinskii, V. P. ; Sukhoroslova, M. M. / 13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring. In: Chemistry of Heterocyclic Compounds. 1984 ; Vol. 20, No. 2. pp. 165-170.
@article{799f9726102c4ddb806959bcdcf4fe07,
title = "13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring",
abstract = "The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.",
author = "Filimonov, {V. D.} and Filippova, {T. A.} and Lopatinskii, {V. P.} and Sukhoroslova, {M. M.}",
year = "1984",
month = "2",
doi = "10.1007/BF00506286",
language = "English",
volume = "20",
pages = "165--170",
journal = "Chemistry of Heterocyclic Compounds",
issn = "0009-3122",
publisher = "Springer New York",
number = "2",

}

TY - JOUR

T1 - 13C NMR spectra of 9-methylcarbazoles and electron conductivity of the carbazole ring

AU - Filimonov, V. D.

AU - Filippova, T. A.

AU - Lopatinskii, V. P.

AU - Sukhoroslova, M. M.

PY - 1984/2

Y1 - 1984/2

N2 - The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.

AB - The effect of substituents in the ring of 9-methylcarbazoles on the 13C NMR chemical shifts was determined. Correlation relationships between the inductive and resonance constants of the substituents and the chemical shifts were found. The transmission properties of the carbazole ring with respect to the electronic effects of substituents in the 3 position were evaluated on the basis of the results obtained. Nonadditivity of the effects of the substituents on the NMR chemical shifts within the limits of one phenyl ring of carbazole relative to monosubstituted benzenes was observed.

UR - http://www.scopus.com/inward/record.url?scp=34250137444&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250137444&partnerID=8YFLogxK

U2 - 10.1007/BF00506286

DO - 10.1007/BF00506286

M3 - Article

VL - 20

SP - 165

EP - 170

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 2

ER -