Sulfated perfluoropolymer-CNF composite as a gas-phase benzene nitration catalyst

Anton P. Koskin, Roman V. Kenzhin, Aleksey A. Vedyagin, Ilya V. Mishakov

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Sulfated perfluoropolymers supported on carbon nanofibers are shown to be active and stable catalysts for gas-phase benzene nitration. The best catalyst exhibits 99.9% selectivity to nitrobenzene with concentration of by-products (mainly nitrophenols) less than 300 ppm.

Original languageEnglish
Pages (from-to)83-86
Number of pages4
JournalCatalysis Communications
Volume53
DOIs
Publication statusPublished - 5 Aug 2014
Externally publishedYes

Fingerprint

Nitration
Benzene
Gases
Nitrophenols
Catalysts
Carbon nanofibers
Nitrobenzene
Catalyst selectivity
Composite materials
Byproducts
nitrobenzene

Keywords

  • Benzene nitration
  • Gas-phase nitration
  • Solid acid catalysis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Process Chemistry and Technology

Cite this

Sulfated perfluoropolymer-CNF composite as a gas-phase benzene nitration catalyst. / Koskin, Anton P.; Kenzhin, Roman V.; Vedyagin, Aleksey A.; Mishakov, Ilya V.

In: Catalysis Communications, Vol. 53, 05.08.2014, p. 83-86.

Research output: Contribution to journalArticle

@article{7d33c880692d47449fecf796f1e93706,
title = "Sulfated perfluoropolymer-CNF composite as a gas-phase benzene nitration catalyst",
abstract = "Sulfated perfluoropolymers supported on carbon nanofibers are shown to be active and stable catalysts for gas-phase benzene nitration. The best catalyst exhibits 99.9{\%} selectivity to nitrobenzene with concentration of by-products (mainly nitrophenols) less than 300 ppm.",
keywords = "Benzene nitration, Gas-phase nitration, Solid acid catalysis",
author = "Koskin, {Anton P.} and Kenzhin, {Roman V.} and Vedyagin, {Aleksey A.} and Mishakov, {Ilya V.}",
year = "2014",
month = "8",
day = "5",
doi = "10.1016/j.catcom.2014.04.026",
language = "English",
volume = "53",
pages = "83--86",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier",

}

TY - JOUR

T1 - Sulfated perfluoropolymer-CNF composite as a gas-phase benzene nitration catalyst

AU - Koskin, Anton P.

AU - Kenzhin, Roman V.

AU - Vedyagin, Aleksey A.

AU - Mishakov, Ilya V.

PY - 2014/8/5

Y1 - 2014/8/5

N2 - Sulfated perfluoropolymers supported on carbon nanofibers are shown to be active and stable catalysts for gas-phase benzene nitration. The best catalyst exhibits 99.9% selectivity to nitrobenzene with concentration of by-products (mainly nitrophenols) less than 300 ppm.

AB - Sulfated perfluoropolymers supported on carbon nanofibers are shown to be active and stable catalysts for gas-phase benzene nitration. The best catalyst exhibits 99.9% selectivity to nitrobenzene with concentration of by-products (mainly nitrophenols) less than 300 ppm.

KW - Benzene nitration

KW - Gas-phase nitration

KW - Solid acid catalysis

UR - http://www.scopus.com/inward/record.url?scp=84901936579&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84901936579&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2014.04.026

DO - 10.1016/j.catcom.2014.04.026

M3 - Article

VL - 53

SP - 83

EP - 86

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -