Study of the separation characteristics of the gallam-exchange systems

Viktor A. Vlasov, Dmitriy G. Vidyaev

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The values of the coefficient α of separation of the alkali metals in the LiGa-NaOH, LiGa-KOH, and KGa-NaOH gallam-exchange systems were determined. The dependences of α on the temperature and concentrations of the phases involved in the exchange were studied for the LiGa-NaOH and LiGa-KOH systems. The kinetic parameters for the exchange of lithium, sodium, and potassium were obtained. The rate constants for the exchange of these elements were described by the Arrhenius equation. The corresponding values of the activation energy and preexponential factor were calculated. The separation and kinetic characteristics obtained were compared to the analogous parameters of amalgam-exchange systems. A gallam-exchange method for separating alkali metals was suggested.

Original languageEnglish
Title of host publicationProceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012
DOIs
Publication statusPublished - 2012
Event2012 7th International Forum on Strategic Technology, IFOST 2012 - Tomsk, Russian Federation
Duration: 18 Sep 201221 Sep 2012

Other

Other2012 7th International Forum on Strategic Technology, IFOST 2012
CountryRussian Federation
CityTomsk
Period18.9.1221.9.12

Fingerprint

Alkali metals
Ion exchange
Mercury amalgams
Kinetic parameters
Potassium
Rate constants
Lithium
Activation energy
Sodium
Kinetics
Temperature

Keywords

  • alkali metals
  • gallam-exchange systems
  • kinetic characteristics
  • separation

ASJC Scopus subject areas

  • Management of Technology and Innovation

Cite this

Vlasov, V. A., & Vidyaev, D. G. (2012). Study of the separation characteristics of the gallam-exchange systems. In Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012 [6357780] https://doi.org/10.1109/IFOST.2012.6357780

Study of the separation characteristics of the gallam-exchange systems. / Vlasov, Viktor A.; Vidyaev, Dmitriy G.

Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357780.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Vlasov, VA & Vidyaev, DG 2012, Study of the separation characteristics of the gallam-exchange systems. in Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012., 6357780, 2012 7th International Forum on Strategic Technology, IFOST 2012, Tomsk, Russian Federation, 18.9.12. https://doi.org/10.1109/IFOST.2012.6357780
Vlasov VA, Vidyaev DG. Study of the separation characteristics of the gallam-exchange systems. In Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357780 https://doi.org/10.1109/IFOST.2012.6357780
Vlasov, Viktor A. ; Vidyaev, Dmitriy G. / Study of the separation characteristics of the gallam-exchange systems. Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012.
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