Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C<sub>60</sub>-[1,9]-Pyrrolidine

Abstract

In this paper new derivatives of fullerene C₆₀ are synthesized. The structure of the molecule structure of the N-Methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-pyrrolidine was proved by NMR of 1H and 13C spectroscopy. The spectral-luminescent properties of N-Methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-pyrrolidine were studied. It was established that the lifetimes of the excited states amounted to 0.31 ns and 0.6 ns, respectively. The photovoltaic properties of organic solar cells with a volumetric heterojunction based on fulleropyrrolidine were studied. It was shown that the use of fulleropyrrolidine as an acceptor was comparable to the VAC for the P3HT: PCBM system.

Original language	English
Title of host publication	Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials
Subtitle of host publication	Applications and Properties, NAP 2017
Publisher	Institute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)	9781538628102
DOIs	https://doi.org/10.1109/NAP.2017.8190253
Publication status	Published - 12 Dec 2017
Externally published	Yes
Event	7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017 - Zatoka, Ukraine Duration: 10 Sep 2017 → 15 Sep 2017

Publication series

Name	Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017
Volume	2017-January

Conference

Conference	7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017
Country	Ukraine
City	Zatoka
Period	10.9.17 → 15.9.17

Keywords

Fluorescence
Fullerene
Poly(3-hexylthiophene)
VAC

ASJC Scopus subject areas

Materials Science (miscellaneous)
Mechanics of Materials

Access to Document

10.1109/NAP.2017.8190253

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Fazylov, S. D., Nurkenov, O. A., Arinova, A. E., Zeinidenov, A. K., Ibrayev, N. K., & Issayeva, A. Z. (2017). Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-Pyrrolidine. In Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017 [8190253] (Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017; Vol. 2017-January). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/NAP.2017.8190253

Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-Pyrrolidine. / Fazylov, S. D.; Nurkenov, O. A.; Arinova, A. E.; Zeinidenov, A. K.; Ibrayev, N. Kh; Issayeva, A. Zh.

Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Institute of Electrical and Electronics Engineers Inc., 2017. 8190253 (Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017; Vol. 2017-January).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Fazylov, SD, Nurkenov, OA, Arinova, AE, Zeinidenov, AK, Ibrayev, NK & Issayeva, AZ 2017, Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-Pyrrolidine. in Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017., 8190253, Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017, vol. 2017-January, Institute of Electrical and Electronics Engineers Inc., 7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017, Zatoka, Ukraine, 10.9.17. https://doi.org/10.1109/NAP.2017.8190253

Fazylov SD, Nurkenov OA, Arinova AE, Zeinidenov AK, Ibrayev NK, Issayeva AZ. Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-Pyrrolidine. In Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Institute of Electrical and Electronics Engineers Inc. 2017. 8190253. (Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017). https://doi.org/10.1109/NAP.2017.8190253

Fazylov, S. D. ; Nurkenov, O. A. ; Arinova, A. E. ; Zeinidenov, A. K. ; Ibrayev, N. Kh ; Issayeva, A. Zh. / Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C₆₀-[1,9]-Pyrrolidine. Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Institute of Electrical and Electronics Engineers Inc., 2017. (Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017).

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title = "Study of the optical and photovoltaic properties of N-methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-Pyrrolidine",

abstract = "In this paper new derivatives of fullerene C60 are synthesized. The structure of the molecule structure of the N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine was proved by NMR of 1H and 13C spectroscopy. The spectral-luminescent properties of N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine were studied. It was established that the lifetimes of the excited states amounted to 0.31 ns and 0.6 ns, respectively. The photovoltaic properties of organic solar cells with a volumetric heterojunction based on fulleropyrrolidine were studied. It was shown that the use of fulleropyrrolidine as an acceptor was comparable to the VAC for the P3HT: PCBM system.",

keywords = "Fluorescence, Fullerene, Poly(3-hexylthiophene), VAC",

author = "Fazylov, {S. D.} and Nurkenov, {O. A.} and Arinova, {A. E.} and Zeinidenov, {A. K.} and Ibrayev, {N. Kh} and Issayeva, {A. Zh}",

year = "2017",

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day = "12",

doi = "10.1109/NAP.2017.8190253",

language = "English",

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publisher = "Institute of Electrical and Electronics Engineers Inc.",

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note = "7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017 ; Conference date: 10-09-2017 Through 15-09-2017",

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AU - Fazylov, S. D.

AU - Nurkenov, O. A.

AU - Arinova, A. E.

AU - Zeinidenov, A. K.

AU - Ibrayev, N. Kh

AU - Issayeva, A. Zh

PY - 2017/12/12

Y1 - 2017/12/12

N2 - In this paper new derivatives of fullerene C60 are synthesized. The structure of the molecule structure of the N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine was proved by NMR of 1H and 13C spectroscopy. The spectral-luminescent properties of N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine were studied. It was established that the lifetimes of the excited states amounted to 0.31 ns and 0.6 ns, respectively. The photovoltaic properties of organic solar cells with a volumetric heterojunction based on fulleropyrrolidine were studied. It was shown that the use of fulleropyrrolidine as an acceptor was comparable to the VAC for the P3HT: PCBM system.

AB - In this paper new derivatives of fullerene C60 are synthesized. The structure of the molecule structure of the N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine was proved by NMR of 1H and 13C spectroscopy. The spectral-luminescent properties of N-Methyl-1-(4-cytisinophenyl) fullerene-C60-[1,9]-pyrrolidine were studied. It was established that the lifetimes of the excited states amounted to 0.31 ns and 0.6 ns, respectively. The photovoltaic properties of organic solar cells with a volumetric heterojunction based on fulleropyrrolidine were studied. It was shown that the use of fulleropyrrolidine as an acceptor was comparable to the VAC for the P3HT: PCBM system.

KW - Fluorescence

KW - Fullerene

KW - Poly(3-hexylthiophene)

KW - VAC

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