Study of the fine rotational structure of the ν₂ band of HDS

O. N. Ulenikov, R. N. Tolchenov, M. Koivusaari, S. Alanko, R. Antilla

Research School of High-Energy Physics

Research output: Contribution to journal › Article › peer-review

Abstract

High-resolution Fourier transform spectra of the monodeuterated species HD³²S and HD³⁴S of hydrogen sulfide have been analyzed in the region of the band ν₂. The bandcenters were estimated as 1032.71519 and 1031.50808 cm^-1 for the HD³²S and HD³⁴S species, respectively. Rotational and centrifugal distortion parameters were obtained, which reproduce the values of upper energy levels within 6.4 × 10^-5 and 8.6 × 10^-5 cm^-1 for the HD³²S and HD³⁴S species, respectively.

Original language	English
Pages (from-to)	1-9
Number of pages	9
Journal	Journal of Molecular Spectroscopy
Volume	170
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1995.1052
Publication status	Published - 1 Jan 1995

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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10.1006/jmsp.1995.1052

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title = "Study of the fine rotational structure of the ν2 band of HDS",

abstract = "High-resolution Fourier transform spectra of the monodeuterated species HD32S and HD34S of hydrogen sulfide have been analyzed in the region of the band ν2. The bandcenters were estimated as 1032.71519 and 1031.50808 cm-1 for the HD32S and HD34S species, respectively. Rotational and centrifugal distortion parameters were obtained, which reproduce the values of upper energy levels within 6.4 × 10-5 and 8.6 × 10-5 cm-1 for the HD32S and HD34S species, respectively.",

author = "Ulenikov, {O. N.} and Tolchenov, {R. N.} and M. Koivusaari and S. Alanko and R. Antilla",

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AU - Ulenikov, O. N.

AU - Tolchenov, R. N.

AU - Koivusaari, M.

AU - Alanko, S.

AU - Antilla, R.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - High-resolution Fourier transform spectra of the monodeuterated species HD32S and HD34S of hydrogen sulfide have been analyzed in the region of the band ν2. The bandcenters were estimated as 1032.71519 and 1031.50808 cm-1 for the HD32S and HD34S species, respectively. Rotational and centrifugal distortion parameters were obtained, which reproduce the values of upper energy levels within 6.4 × 10-5 and 8.6 × 10-5 cm-1 for the HD32S and HD34S species, respectively.

AB - High-resolution Fourier transform spectra of the monodeuterated species HD32S and HD34S of hydrogen sulfide have been analyzed in the region of the band ν2. The bandcenters were estimated as 1032.71519 and 1031.50808 cm-1 for the HD32S and HD34S species, respectively. Rotational and centrifugal distortion parameters were obtained, which reproduce the values of upper energy levels within 6.4 × 10-5 and 8.6 × 10-5 cm-1 for the HD32S and HD34S species, respectively.

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