High-resolution Fourier transform spectra of the monodeuterated species HD32S and HD34S of hydrogen sulfide have been analyzed in the region of the band ν2. The bandcenters were estimated as 1032.71519 and 1031.50808 cm-1 for the HD32S and HD34S species, respectively. Rotational and centrifugal distortion parameters were obtained, which reproduce the values of upper energy levels within 6.4 × 10-5 and 8.6 × 10-5 cm-1 for the HD32S and HD34S species, respectively.
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Physical and Theoretical Chemistry