Abstract
Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.
| Original language | English |
|---|---|
| Pages (from-to) | 799-803 |
| Number of pages | 5 |
| Journal | Russian Journal of General Chemistry |
| Volume | 84 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2014 |
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Keywords
- photolysis
- potassium trithiosulfatocadmate
- spectroscopy
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol. / Egorov, N. B.; Eremin, L. P.; Obmuch, K. B.; Usov, V. F.
In: Russian Journal of General Chemistry, Vol. 84, No. 5, 2014, p. 799-803.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol
AU - Egorov, N. B.
AU - Eremin, L. P.
AU - Obmuch, K. B.
AU - Usov, V. F.
PY - 2014
Y1 - 2014
N2 - Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.
AB - Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.
KW - photolysis
KW - potassium trithiosulfatocadmate
KW - spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=84903976372&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84903976372&partnerID=8YFLogxK
U2 - 10.1134/S1070363214050016
DO - 10.1134/S1070363214050016
M3 - Article
VL - 84
SP - 799
EP - 803
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 5
ER -