Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol

N. B. Egorov, L. P. Eremin, K. B. Obmuch, V. F. Usov

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Abstract

Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

Original languageEnglish
Pages (from-to)799-803
Number of pages5
JournalRussian Journal of General Chemistry
Volume84
Issue number5
DOIs
Publication statusPublished - 2014

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Keywords

  • photolysis
  • potassium trithiosulfatocadmate
  • spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)

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