Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol

Abstract

Photolysis of K₄[Cd(S₂O₃)₃] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

Original language	English
Pages (from-to)	799-803
Number of pages	5
Journal	Russian Journal of General Chemistry
Volume	84
Issue number	5
DOIs	https://doi.org/10.1134/S1070363214050016
Publication status	Published - 2014

Keywords

photolysis
potassium trithiosulfatocadmate
spectroscopy

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1134/S1070363214050016

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Egorov, N. B., Eremin, L. P., Obmuch, K. B., & Usov, V. F. (2014). Study of photolysis of K₄[Cd(S₂O₃) ₃] solutions in aqueous isopropanol. Russian Journal of General Chemistry, 84(5), 799-803. https://doi.org/10.1134/S1070363214050016

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abstract = "Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.",

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author = "Egorov, {N. B.} and Eremin, {L. P.} and Obmuch, {K. B.} and Usov, {V. F.}",

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AU - Obmuch, K. B.

AU - Usov, V. F.

PY - 2014

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AB - Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

KW - photolysis

KW - potassium trithiosulfatocadmate

KW - spectroscopy

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