Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol

Abstract

Photolysis of K₄[Cd(S₂O₃)₃] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

Original language	English
Pages (from-to)	799-803
Number of pages	5
Journal	Russian Journal of General Chemistry
Volume	84
Issue number	5
DOIs	https://doi.org/10.1134/S1070363214050016
Publication status	Published - 2014

Keywords

photolysis
potassium trithiosulfatocadmate
spectroscopy

ASJC Scopus subject areas

Chemistry(all)

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10.1134/S1070363214050016

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title = "Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol",

abstract = "Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.",

keywords = "photolysis, potassium trithiosulfatocadmate, spectroscopy",

author = "Egorov, {N. B.} and Eremin, {L. P.} and Obmuch, {K. B.} and Usov, {V. F.}",

year = "2014",

doi = "10.1134/S1070363214050016",

language = "English",

volume = "84",

pages = "799--803",

journal = "Russian Journal of General Chemistry",

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T1 - Study of photolysis of K4[Cd(S2O3) 3] solutions in aqueous isopropanol

AU - Egorov, N. B.

AU - Eremin, L. P.

AU - Obmuch, K. B.

AU - Usov, V. F.

PY - 2014

Y1 - 2014

N2 - Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

AB - Photolysis of K4[Cd(S2O3)3] solutions in aqueous isopropanol under irradiation with high-pressure mercury-quartz lamp has been studied by spectroscopy methods. The photolysis products have been identified by X-ray diffraction analysis; their formation mechanism has been suggested. The primary photolysis product is nanosized CdS, its irradiation initiating further redox transformations of the solution components to give the final products.

KW - photolysis

KW - potassium trithiosulfatocadmate

KW - spectroscopy

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JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 5

ER -

Study of photolysis of K₄[Cd(S₂O₃) ₃] solutions in aqueous isopropanol

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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