Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions

The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂

O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, Yu B. Morzhikova, C. Maul, C. Sydow, S. Bauerecker

Research School of High-Energy Physics

Research output: Contribution to journal › Article

Abstract

Transitions belonging to the three “hot” bands of the S¹⁸O₂ molecule, ν₁+ν₂+ν₃−ν₂ (621 transitions with the values of quantum numbers J^max=49 and K_a ^max=14), 2ν₁+ν₂−ν₂ (332 transitions with J^max=42 and K_a ^max=12) and 2ν₂+ν₃−ν₂ (15 transitions with J^max=14 and K_a=8 and 9), were assigned in the spectral 2100–2700 cm⁻¹ region. This enabled for the first time to get high accurate values of 388, 185 and 13 ro-vibrational energies for the highly excited vibrational states (111), (210) and (021), respectively. A weighted fit analysis using the obtained ro-vibrational energies allowed us to generate a set of 20 fitted parameters which reproduce the initial 586 energy values (about 970 assigned experimental transitions) with the d_rms deviations of 1.9×10⁻⁴cm⁻¹, 2.8×10⁻⁴ cm⁻¹ and 2.5×10⁻⁴ cm⁻¹ for the states (111), (210) and (021).

Original language	English
Pages (from-to)	159-164
Number of pages	6
Journal	Journal of Quantitative Spectroscopy and Radiative Transfer
Volume	196
DOIs	https://doi.org/10.1016/j.jqsrt.2017.04.004
Publication status	Published - 1 Jul 2017

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vibrational states

Molecules

quantum numbers

energy

deviation

molecules

Keywords

SO
High-resolution spectra
Spectroscopic parameters
Sulfur dioxide

ASJC Scopus subject areas

Radiation
Atomic and Molecular Physics, and Optics
Spectroscopy

Cite this

Ulenikov, O. N., Gromova, O. V., Bekhtereva, E. S., Morzhikova, Y. B., Maul, C., Sydow, C., & Bauerecker, S. (2017). Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions: The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂. Journal of Quantitative Spectroscopy and Radiative Transfer, 196, 159-164. https://doi.org/10.1016/j.jqsrt.2017.04.004

Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions : The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂. / Ulenikov, O. N.; Gromova, O. V.; Bekhtereva, E. S.; Morzhikova, Yu B.; Maul, C.; Sydow, C.; Bauerecker, S.

In: Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 196, 01.07.2017, p. 159-164.

Research output: Contribution to journal › Article

Ulenikov, ON , Gromova, OV , Bekhtereva, ES, Morzhikova, YB, Maul, C, Sydow, C & Bauerecker, S 2017, 'Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions: The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂', Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 196, pp. 159-164. https://doi.org/10.1016/j.jqsrt.2017.04.004

Ulenikov ON , Gromova OV , Bekhtereva ES, Morzhikova YB, Maul C, Sydow C et al. Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions: The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂. Journal of Quantitative Spectroscopy and Radiative Transfer. 2017 Jul 1;196:159-164. https://doi.org/10.1016/j.jqsrt.2017.04.004

Ulenikov, O. N. ; Gromova, O. V. ; Bekhtereva, E. S. ; Morzhikova, Yu B. ; Maul, C. ; Sydow, C. ; Bauerecker, S. / Study of highly excited ro-vibrational states of S¹⁸O₂ from “hot” transitions : The bands ν₁+ν₂+ν₃−ν₂, 2ν₁+ν₂−ν₂, and 2ν₂+ν₃−ν₂. In: Journal of Quantitative Spectroscopy and Radiative Transfer. 2017 ; Vol. 196. pp. 159-164.

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title = "Study of highly excited ro-vibrational states of S18O2 from “hot” transitions: The bands ν1+ν2+ν3−ν2, 2ν1+ν2−ν2, and 2ν2+ν3−ν2",

abstract = "Transitions belonging to the three “hot” bands of the S18O2 molecule, ν1+ν2+ν3−ν2 (621 transitions with the values of quantum numbers Jmax=49 and Ka max=14), 2ν1+ν2−ν2 (332 transitions with Jmax=42 and Ka max=12) and 2ν2+ν3−ν2 (15 transitions with Jmax=14 and Ka=8 and 9), were assigned in the spectral 2100–2700 cm−1 region. This enabled for the first time to get high accurate values of 388, 185 and 13 ro-vibrational energies for the highly excited vibrational states (111), (210) and (021), respectively. A weighted fit analysis using the obtained ro-vibrational energies allowed us to generate a set of 20 fitted parameters which reproduce the initial 586 energy values (about 970 assigned experimental transitions) with the drms deviations of 1.9×10−4cm−1, 2.8×10−4 cm−1 and 2.5×10−4 cm−1 for the states (111), (210) and (021).",

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author = "Ulenikov, {O. N.} and Gromova, {O. V.} and Bekhtereva, {E. S.} and Morzhikova, {Yu B.} and C. Maul and C. Sydow and S. Bauerecker",

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AU - Ulenikov, O. N.

AU - Gromova, O. V.

AU - Bekhtereva, E. S.

AU - Morzhikova, Yu B.

AU - Maul, C.

AU - Sydow, C.

AU - Bauerecker, S.

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N2 - Transitions belonging to the three “hot” bands of the S18O2 molecule, ν1+ν2+ν3−ν2 (621 transitions with the values of quantum numbers Jmax=49 and Ka max=14), 2ν1+ν2−ν2 (332 transitions with Jmax=42 and Ka max=12) and 2ν2+ν3−ν2 (15 transitions with Jmax=14 and Ka=8 and 9), were assigned in the spectral 2100–2700 cm−1 region. This enabled for the first time to get high accurate values of 388, 185 and 13 ro-vibrational energies for the highly excited vibrational states (111), (210) and (021), respectively. A weighted fit analysis using the obtained ro-vibrational energies allowed us to generate a set of 20 fitted parameters which reproduce the initial 586 energy values (about 970 assigned experimental transitions) with the drms deviations of 1.9×10−4cm−1, 2.8×10−4 cm−1 and 2.5×10−4 cm−1 for the states (111), (210) and (021).

AB - Transitions belonging to the three “hot” bands of the S18O2 molecule, ν1+ν2+ν3−ν2 (621 transitions with the values of quantum numbers Jmax=49 and Ka max=14), 2ν1+ν2−ν2 (332 transitions with Jmax=42 and Ka max=12) and 2ν2+ν3−ν2 (15 transitions with Jmax=14 and Ka=8 and 9), were assigned in the spectral 2100–2700 cm−1 region. This enabled for the first time to get high accurate values of 388, 185 and 13 ro-vibrational energies for the highly excited vibrational states (111), (210) and (021), respectively. A weighted fit analysis using the obtained ro-vibrational energies allowed us to generate a set of 20 fitted parameters which reproduce the initial 586 energy values (about 970 assigned experimental transitions) with the drms deviations of 1.9×10−4cm−1, 2.8×10−4 cm−1 and 2.5×10−4 cm−1 for the states (111), (210) and (021).

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Access to Document

10.1016/j.jqsrt.2017.04.004