Study of catalyst activity in the extensive oxidation of butane and the state of platinum in lanthanum- and cerium-modified Pt/Al2 O3

V. A. Drozdov, P. G. Tsyrul'nikov, A. N. Pestryakov, A. A. Davydov, V. V. Popovskii

Research output: Contribution to journalArticle

Abstract

An effect was demonstrated for the addition of lanthanum and cerium oxides to Pt/Al2O3 catalysts on the catalyst activity in the extensive oxidation of butane. Independently of the rate of the butane and oxygen concentrations in the gas phase, the specific catalyst activity (SCA) per m2 Pt of the modified samples is less than that of the Pt/Al2O3 catalyst. The addition of lanthanum and cerium significantly increases the dispersion and stability of the supported platinum upon overheating. The IR spectra of the Co molecular probe were used to establish the electronic states of the surface platinum atoms in the samples studied after various treatments.

Original languageEnglish
Pages (from-to)420-423
Number of pages4
JournalKinetics and Catalysis
Volume29
Issue number2 pt 2
Publication statusPublished - Oct 1988

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Cerium
Lanthanum
Platinum
Butane
butanes
cerium
Catalyst
lanthanum
Oxidation
Catalyst activity
platinum
catalysts
Molecular Probes
oxidation
Catalysts
Electronic states
Gases
Oxygen
lanthanum oxides
cerium oxides

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Study of catalyst activity in the extensive oxidation of butane and the state of platinum in lanthanum- and cerium-modified Pt/Al2 O3 . / Drozdov, V. A.; Tsyrul'nikov, P. G.; Pestryakov, A. N.; Davydov, A. A.; Popovskii, V. V.

In: Kinetics and Catalysis, Vol. 29, No. 2 pt 2, 10.1988, p. 420-423.

Research output: Contribution to journalArticle

Drozdov, V. A. ; Tsyrul'nikov, P. G. ; Pestryakov, A. N. ; Davydov, A. A. ; Popovskii, V. V. / Study of catalyst activity in the extensive oxidation of butane and the state of platinum in lanthanum- and cerium-modified Pt/Al2 O3 In: Kinetics and Catalysis. 1988 ; Vol. 29, No. 2 pt 2. pp. 420-423.
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