Structure of the paramagnetic products of thiocyanate photolysis at 77 K

L. P. Eremin, O. Kh Poleshchuk, V. A. Poluboyarov, L. V. Babovskaya, A. E. Lapin

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    Solid paramagnetic products of thiocyanate photolysis were studied at 77 K by EPR and diffuse reflectance spectroscopy. Ab initio calculations of the electronic structure of these products have been carried out. Direct UV irradiation can generate the SCN 0 radical due to ionization of the thiocyanate ion. Interaction of the SCN 0 radical with the neighboring thiocyanate ion forms another radical product of photolysis - (SCN) 2 - radical ion.

    Original languageEnglish
    Pages (from-to)404-409
    Number of pages6
    JournalJournal of Structural Chemistry
    Volume44
    Issue number3
    DOIs
    Publication statusPublished - May 2003

    Fingerprint

    Photolysis
    photolysis
    Ions
    products
    ions
    Ionization
    Electronic structure
    Paramagnetic resonance
    Irradiation
    Spectroscopy
    electronic structure
    reflectance
    ionization
    irradiation
    thiocyanate
    spectroscopy
    interactions

    Keywords

    • Density functional theory
    • EPR spectra
    • Photolysis
    • Thiocyanates

    ASJC Scopus subject areas

    • Inorganic Chemistry
    • Physical and Theoretical Chemistry

    Cite this

    Eremin, L. P., Poleshchuk, O. K., Poluboyarov, V. A., Babovskaya, L. V., & Lapin, A. E. (2003). Structure of the paramagnetic products of thiocyanate photolysis at 77 K. Journal of Structural Chemistry, 44(3), 404-409. https://doi.org/10.1023/B:JORY.0000009667.51492.c8

    Structure of the paramagnetic products of thiocyanate photolysis at 77 K. / Eremin, L. P.; Poleshchuk, O. Kh; Poluboyarov, V. A.; Babovskaya, L. V.; Lapin, A. E.

    In: Journal of Structural Chemistry, Vol. 44, No. 3, 05.2003, p. 404-409.

    Research output: Contribution to journalArticle

    Eremin, LP, Poleshchuk, OK, Poluboyarov, VA, Babovskaya, LV & Lapin, AE 2003, 'Structure of the paramagnetic products of thiocyanate photolysis at 77 K', Journal of Structural Chemistry, vol. 44, no. 3, pp. 404-409. https://doi.org/10.1023/B:JORY.0000009667.51492.c8
    Eremin, L. P. ; Poleshchuk, O. Kh ; Poluboyarov, V. A. ; Babovskaya, L. V. ; Lapin, A. E. / Structure of the paramagnetic products of thiocyanate photolysis at 77 K. In: Journal of Structural Chemistry. 2003 ; Vol. 44, No. 3. pp. 404-409.
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