Abstract
The aim of study is to demonstrate that separation of solvated ions in solution of mix of salts under the action of external periodic electric field happens because of around ions there are formed clusters consisting of molecules of solvent and the sizes of such clusters have dimensions ∼ 0.1 μm. In investigations the sizes of clusters theoretically were defined and experimentally value of frequency of external electric field which action excites the effect of separation of the solvated ions was defined. Experiments were done in the Technical Physics Chair of the National Research Tomsk Polytechnic University. At theoretical determination of the dimensions of clusters Poisson's equation was solved and was considered that polar molecules of solvent are oriented under the action of electric field of an ion. The chemical composition of samples of solutions was determined by means of the spectrophotometry and he X-ray excited fluorescent radiation analysis method. Theoretical estimates and results of experiments confirmed the assumption that clusters which are formed around ions in solutions have the dimensions ∼ 0.1 μm. Results of investigation testify that placing of volume distributed electric charge of ion in dielectric liquid is accompanied by formation of the supramolecular particles, which we called »clusters», linear sizes of which is significantly more than first and second radiuses of solvation (∼ 1 Angstrom) and reach size ∼ 0.1 μm. At such sizes inertial properties of clusters and their natural frequencies give the chance to operate their movement by means of action of external electric field on solution.
| Original language | English |
|---|---|
| Title of host publication | Proceedings of SPIE - The International Society for Optical Engineering |
| Publisher | SPIE |
| Volume | 9810 |
| ISBN (Print) | 9781510600515 |
| DOIs | |
| Publication status | Published - 2015 |
| Event | International Conference on Atomic and Molecular Pulsed Lasers XII - Tomsk, Russian Federation Duration: 13 Sep 2015 → 18 Sep 2015 |
Other
| Other | International Conference on Atomic and Molecular Pulsed Lasers XII |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 13.9.15 → 18.9.15 |
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Keywords
- cation
- directed motion
- electric field
- separation
- Solution
- solvation
ASJC Scopus subject areas
- Applied Mathematics
- Computer Science Applications
- Electrical and Electronic Engineering
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
Cite this
Structure of salts solution in polar dielectric liquids and electrically induced separation of solvated ions. / Shamanin, Igor V.; Kazaryan, Mishik A.; Sachkov, Victor I.
Proceedings of SPIE - The International Society for Optical Engineering. Vol. 9810 SPIE, 2015. 981019.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Structure of salts solution in polar dielectric liquids and electrically induced separation of solvated ions
AU - Shamanin, Igor V.
AU - Kazaryan, Mishik A.
AU - Sachkov, Victor I.
PY - 2015
Y1 - 2015
N2 - The aim of study is to demonstrate that separation of solvated ions in solution of mix of salts under the action of external periodic electric field happens because of around ions there are formed clusters consisting of molecules of solvent and the sizes of such clusters have dimensions ∼ 0.1 μm. In investigations the sizes of clusters theoretically were defined and experimentally value of frequency of external electric field which action excites the effect of separation of the solvated ions was defined. Experiments were done in the Technical Physics Chair of the National Research Tomsk Polytechnic University. At theoretical determination of the dimensions of clusters Poisson's equation was solved and was considered that polar molecules of solvent are oriented under the action of electric field of an ion. The chemical composition of samples of solutions was determined by means of the spectrophotometry and he X-ray excited fluorescent radiation analysis method. Theoretical estimates and results of experiments confirmed the assumption that clusters which are formed around ions in solutions have the dimensions ∼ 0.1 μm. Results of investigation testify that placing of volume distributed electric charge of ion in dielectric liquid is accompanied by formation of the supramolecular particles, which we called »clusters», linear sizes of which is significantly more than first and second radiuses of solvation (∼ 1 Angstrom) and reach size ∼ 0.1 μm. At such sizes inertial properties of clusters and their natural frequencies give the chance to operate their movement by means of action of external electric field on solution.
AB - The aim of study is to demonstrate that separation of solvated ions in solution of mix of salts under the action of external periodic electric field happens because of around ions there are formed clusters consisting of molecules of solvent and the sizes of such clusters have dimensions ∼ 0.1 μm. In investigations the sizes of clusters theoretically were defined and experimentally value of frequency of external electric field which action excites the effect of separation of the solvated ions was defined. Experiments were done in the Technical Physics Chair of the National Research Tomsk Polytechnic University. At theoretical determination of the dimensions of clusters Poisson's equation was solved and was considered that polar molecules of solvent are oriented under the action of electric field of an ion. The chemical composition of samples of solutions was determined by means of the spectrophotometry and he X-ray excited fluorescent radiation analysis method. Theoretical estimates and results of experiments confirmed the assumption that clusters which are formed around ions in solutions have the dimensions ∼ 0.1 μm. Results of investigation testify that placing of volume distributed electric charge of ion in dielectric liquid is accompanied by formation of the supramolecular particles, which we called »clusters», linear sizes of which is significantly more than first and second radiuses of solvation (∼ 1 Angstrom) and reach size ∼ 0.1 μm. At such sizes inertial properties of clusters and their natural frequencies give the chance to operate their movement by means of action of external electric field on solution.
KW - cation
KW - directed motion
KW - electric field
KW - separation
KW - Solution
KW - solvation
UR - http://www.scopus.com/inward/record.url?scp=84957991272&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84957991272&partnerID=8YFLogxK
U2 - 10.1117/12.2225223
DO - 10.1117/12.2225223
M3 - Conference contribution
AN - SCOPUS:84957991272
SN - 9781510600515
VL - 9810
BT - Proceedings of SPIE - The International Society for Optical Engineering
PB - SPIE
ER -