Abstract
Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10 S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains.
| Original language | English |
|---|---|
| Pages (from-to) | 19-25 |
| Number of pages | 7 |
| Journal | Applied Surface Science |
| Volume | 483 |
| DOIs | |
| Publication status | Published - 31 Jul 2019 |
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Keywords
- Active gas phase
- Impedance spectroscopy
- Low-energy electron beam deposition
- Polyaniline-based nanocomposite coating
ASJC Scopus subject areas
- Surfaces, Coatings and Films
Cite this
Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam. / Rogachev; Yarmolenko; Rogachev, V. V.; Xiaohong, Jiang; Cao, Hongtao; Lysenko, E. N.; Surzhikov, A. P.
In: Applied Surface Science, Vol. 483, 31.07.2019, p. 19-25.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam
AU - Rogachev, null
AU - Yarmolenko,
AU - Rogachev, V. V.
AU - Xiaohong, Jiang
AU - Cao, Hongtao
AU - Lysenko, E. N.
AU - Surzhikov, A. P.
PY - 2019/7/31
Y1 - 2019/7/31
N2 - Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10 S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains.
AB - Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10 S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains.
KW - Active gas phase
KW - Impedance spectroscopy
KW - Low-energy electron beam deposition
KW - Polyaniline-based nanocomposite coating
UR - http://www.scopus.com/inward/record.url?scp=85063514554&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85063514554&partnerID=8YFLogxK
U2 - 10.1016/j.apsusc.2019.03.159
DO - 10.1016/j.apsusc.2019.03.159
M3 - Article
AN - SCOPUS:85063514554
VL - 483
SP - 19
EP - 25
JO - Applied Surface Science
JF - Applied Surface Science
SN - 0169-4332
ER -