Structural-phase and morphological characteristics of silver catalysts on modified ceramic supports for selective oxidation of alcohols

Abstract

New ceramic materials based on silicon nitride and obtained by self-propagating high-temperature (SPHT) synthesis were investigated. The Si₃N₄ materials modified with Zr and Al compounds were used as supports for silver-containing catalysts of selective oxidation of ethyleneglycol into glyoxal. The procedure for the synthesis of supported silver-containing catalysts affected the structural and morphological states of the active component before and after the catalytic reaction.

Original language	English
Pages (from-to)	376-381
Number of pages	6
Journal	Russian Journal of Physical Chemistry A
Volume	87
Issue number	3
DOIs	https://doi.org/10.1134/S0036024413030060
Publication status	Published - 1 Mar 2013

Keywords

oxidation
self-propagating high-temperature synthesis
silicon nitride
silver

ASJC Scopus subject areas

Physical and Theoretical Chemistry

Access to Document

10.1134/S0036024413030060

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Blokhina, A. S., Kurzina, I. A., Chukhlomina, L. N., Vitushkina, O. G., Smirnov, A. I., Bataev, I. A., Veselov, S. V., & Vodyankina, O. V. (2013). Structural-phase and morphological characteristics of silver catalysts on modified ceramic supports for selective oxidation of alcohols. Russian Journal of Physical Chemistry A, 87(3), 376-381. https://doi.org/10.1134/S0036024413030060

Structural-phase and morphological characteristics of silver catalysts on modified ceramic supports for selective oxidation of alcohols. / Blokhina, A. S.; Kurzina, I. A.; Chukhlomina, L. N.; Vitushkina, O. G.; Smirnov, A. I.; Bataev, I. A.; Veselov, S. V.; Vodyankina, O. V.

In: Russian Journal of Physical Chemistry A, Vol. 87, No. 3, 01.03.2013, p. 376-381.

Research output: Contribution to journal › Article

Blokhina, AS, Kurzina, IA, Chukhlomina, LN, Vitushkina, OG, Smirnov, AI, Bataev, IA, Veselov, SV & Vodyankina, OV 2013, 'Structural-phase and morphological characteristics of silver catalysts on modified ceramic supports for selective oxidation of alcohols', Russian Journal of Physical Chemistry A, vol. 87, no. 3, pp. 376-381. https://doi.org/10.1134/S0036024413030060

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title = "Structural-phase and morphological characteristics of silver catalysts on modified ceramic supports for selective oxidation of alcohols",

abstract = "New ceramic materials based on silicon nitride and obtained by self-propagating high-temperature (SPHT) synthesis were investigated. The Si3N4 materials modified with Zr and Al compounds were used as supports for silver-containing catalysts of selective oxidation of ethyleneglycol into glyoxal. The procedure for the synthesis of supported silver-containing catalysts affected the structural and morphological states of the active component before and after the catalytic reaction.",

keywords = "oxidation, self-propagating high-temperature synthesis, silicon nitride, silver",

author = "Blokhina, {A. S.} and Kurzina, {I. A.} and Chukhlomina, {L. N.} and Vitushkina, {O. G.} and Smirnov, {A. I.} and Bataev, {I. A.} and Veselov, {S. V.} and Vodyankina, {O. V.}",

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AU - Blokhina, A. S.

AU - Kurzina, I. A.

AU - Chukhlomina, L. N.

AU - Vitushkina, O. G.

AU - Smirnov, A. I.

AU - Bataev, I. A.

AU - Veselov, S. V.

AU - Vodyankina, O. V.

PY - 2013/3/1

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N2 - New ceramic materials based on silicon nitride and obtained by self-propagating high-temperature (SPHT) synthesis were investigated. The Si3N4 materials modified with Zr and Al compounds were used as supports for silver-containing catalysts of selective oxidation of ethyleneglycol into glyoxal. The procedure for the synthesis of supported silver-containing catalysts affected the structural and morphological states of the active component before and after the catalytic reaction.

AB - New ceramic materials based on silicon nitride and obtained by self-propagating high-temperature (SPHT) synthesis were investigated. The Si3N4 materials modified with Zr and Al compounds were used as supports for silver-containing catalysts of selective oxidation of ethyleneglycol into glyoxal. The procedure for the synthesis of supported silver-containing catalysts affected the structural and morphological states of the active component before and after the catalytic reaction.

KW - oxidation

KW - self-propagating high-temperature synthesis

KW - silicon nitride

KW - silver

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