Stable nitroxyl radicals with triple bonds

4-acetylenyl-3-imidazoline-3-oxide-1-oxyls

Sergei F. Vasilevsky, Svetlana V. Klyatskaya, Olga L. Korovnikova, Svetlana A. Amitina, Dmitri V. Stass, Igor A. Grigor'ev, José Elguero

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Cross-coupling reaction of 1-hydroxy-2,2,5,5-tetramethyl-4-[2-(p-iodophenyl)vinyl]-3-imidazoline-3-oxide with copper(I) salts of 1-aryl(hetaryl)alkynes leads to the corresponding 2,2,5,5-tetramethyl-4-[2-(p-aryl(hetaryl)ethynylphenyl)vinyl]-3-imidazoline-3-oxide-1-oxyls in high yields.

Original languageEnglish
Pages (from-to)4597-4602
Number of pages6
JournalTetrahedron
Volume62
Issue number18
DOIs
Publication statusPublished - 1 May 2006
Externally publishedYes

Fingerprint

Imidazolines
Oxides
Alkynes
Cross Reactions
Copper
Salts
nitroxyl

Keywords

  • 3-Imidazoline nitroxides
  • Acetylenes
  • Copper acetylides
  • Cross-coupling reaction

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Vasilevsky, S. F., Klyatskaya, S. V., Korovnikova, O. L., Amitina, S. A., Stass, D. V., Grigor'ev, I. A., & Elguero, J. (2006). Stable nitroxyl radicals with triple bonds: 4-acetylenyl-3-imidazoline-3-oxide-1-oxyls. Tetrahedron, 62(18), 4597-4602. https://doi.org/10.1016/j.tet.2006.02.036

Stable nitroxyl radicals with triple bonds : 4-acetylenyl-3-imidazoline-3-oxide-1-oxyls. / Vasilevsky, Sergei F.; Klyatskaya, Svetlana V.; Korovnikova, Olga L.; Amitina, Svetlana A.; Stass, Dmitri V.; Grigor'ev, Igor A.; Elguero, José.

In: Tetrahedron, Vol. 62, No. 18, 01.05.2006, p. 4597-4602.

Research output: Contribution to journalArticle

Vasilevsky, SF, Klyatskaya, SV, Korovnikova, OL, Amitina, SA, Stass, DV, Grigor'ev, IA & Elguero, J 2006, 'Stable nitroxyl radicals with triple bonds: 4-acetylenyl-3-imidazoline-3-oxide-1-oxyls', Tetrahedron, vol. 62, no. 18, pp. 4597-4602. https://doi.org/10.1016/j.tet.2006.02.036
Vasilevsky SF, Klyatskaya SV, Korovnikova OL, Amitina SA, Stass DV, Grigor'ev IA et al. Stable nitroxyl radicals with triple bonds: 4-acetylenyl-3-imidazoline-3-oxide-1-oxyls. Tetrahedron. 2006 May 1;62(18):4597-4602. https://doi.org/10.1016/j.tet.2006.02.036
Vasilevsky, Sergei F. ; Klyatskaya, Svetlana V. ; Korovnikova, Olga L. ; Amitina, Svetlana A. ; Stass, Dmitri V. ; Grigor'ev, Igor A. ; Elguero, José. / Stable nitroxyl radicals with triple bonds : 4-acetylenyl-3-imidazoline-3-oxide-1-oxyls. In: Tetrahedron. 2006 ; Vol. 62, No. 18. pp. 4597-4602.
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