Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane

Abstract

Iron(II) complexes with tris(3,5-dimethylpyrazol-1-yl)methane {HC(3,5-Me ₂Pz) ₃} of the composition [Fe{HC(3,5-Me ₂Pz) ₃} ₂]A _m • nH ₂O (A = Cl ^- (I), ClO4 (II), SO ^2- ₄ (III), CF3SO3 (IV), m = 1, 2, n = 0.1) are synthesized. The compounds are studied by static magnetic susceptibility, IR and diffuse reflectance spectroscopy, and X-ray structure analysis. The crystal structures of two polymorphous modifications of the [Fe{HC(3,5-Me ₂Pz) ₃} ₂](ClO ₄) ₂ (IIa and IIb) and [Fe{HC(3,5-Me ₂Pz) ₃} ₂](CF ₃SO ₃) ₂ (IV) complexes are determined. The temperature dependence (J. _eff(T) shows that the spin crossover ¹A1 ⁵T ₂ is observed in the polycrystalline phase of complex I and in one of the single-crystal phases of complex II (IIa) and is accompanied by thermochromism (the change of the dark pink color to white).

Original language	English
Pages (from-to)	507-514
Number of pages	8
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	38
Issue number	8
DOIs	https://doi.org/10.1134/S1070328412070081
Publication status	Published - 1 Aug 2012
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Lavrenova, L. G., Strekalova, A. D., Virovets, A. V., Piryazev, D. A., Daletskii, V. A., Sheludyakova, L. A., Mikhailovskaya, T. F., & Vasilevskii, S. F. (2012). Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 38(8), 507-514. https://doi.org/10.1134/S1070328412070081

Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane. / Lavrenova, L. G.; Strekalova, A. D.; Virovets, A. V.; Piryazev, D. A.; Daletskii, V. A.; Sheludyakova, L. A.; Mikhailovskaya, T. F.; Vasilevskii, S. F.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 38, No. 8, 01.08.2012, p. 507-514.

Research output: Contribution to journal › Article

Lavrenova, LG, Strekalova, AD, Virovets, AV, Piryazev, DA, Daletskii, VA, Sheludyakova, LA, Mikhailovskaya, TF & Vasilevskii, SF 2012, 'Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 38, no. 8, pp. 507-514. https://doi.org/10.1134/S1070328412070081

Lavrenova, L. G. ; Strekalova, A. D. ; Virovets, A. V. ; Piryazev, D. A. ; Daletskii, V. A. ; Sheludyakova, L. A. ; Mikhailovskaya, T. F. ; Vasilevskii, S. F. / Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2012 ; Vol. 38, No. 8. pp. 507-514.

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title = "Spin crossover in the coordination compounds of iron(II) with tris(3,5-dimethylpyrazol-1-yl)methane",

abstract = "Iron(II) complexes with tris(3,5-dimethylpyrazol-1-yl)methane {HC(3,5-Me 2Pz) 3} of the composition [Fe{HC(3,5-Me 2Pz) 3} 2]A m • nH 2O (A = Cl - (I), ClO4 (II), SO 2- 4 (III), CF3SO3 (IV), m = 1, 2, n = 0.1) are synthesized. The compounds are studied by static magnetic susceptibility, IR and diffuse reflectance spectroscopy, and X-ray structure analysis. The crystal structures of two polymorphous modifications of the [Fe{HC(3,5-Me 2Pz) 3} 2](ClO 4) 2 (IIa and IIb) and [Fe{HC(3,5-Me 2Pz) 3} 2](CF 3SO 3) 2 (IV) complexes are determined. The temperature dependence (J. eff(T) shows that the spin crossover 1A1 5T 2 is observed in the polycrystalline phase of complex I and in one of the single-crystal phases of complex II (IIa) and is accompanied by thermochromism (the change of the dark pink color to white).",

author = "Lavrenova, {L. G.} and Strekalova, {A. D.} and Virovets, {A. V.} and Piryazev, {D. A.} and Daletskii, {V. A.} and Sheludyakova, {L. A.} and Mikhailovskaya, {T. F.} and Vasilevskii, {S. F.}",

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AU - Lavrenova, L. G.

AU - Strekalova, A. D.

AU - Virovets, A. V.

AU - Piryazev, D. A.

AU - Daletskii, V. A.

AU - Sheludyakova, L. A.

AU - Mikhailovskaya, T. F.

AU - Vasilevskii, S. F.

PY - 2012/8/1

Y1 - 2012/8/1

N2 - Iron(II) complexes with tris(3,5-dimethylpyrazol-1-yl)methane {HC(3,5-Me 2Pz) 3} of the composition [Fe{HC(3,5-Me 2Pz) 3} 2]A m • nH 2O (A = Cl - (I), ClO4 (II), SO 2- 4 (III), CF3SO3 (IV), m = 1, 2, n = 0.1) are synthesized. The compounds are studied by static magnetic susceptibility, IR and diffuse reflectance spectroscopy, and X-ray structure analysis. The crystal structures of two polymorphous modifications of the [Fe{HC(3,5-Me 2Pz) 3} 2](ClO 4) 2 (IIa and IIb) and [Fe{HC(3,5-Me 2Pz) 3} 2](CF 3SO 3) 2 (IV) complexes are determined. The temperature dependence (J. eff(T) shows that the spin crossover 1A1 5T 2 is observed in the polycrystalline phase of complex I and in one of the single-crystal phases of complex II (IIa) and is accompanied by thermochromism (the change of the dark pink color to white).

AB - Iron(II) complexes with tris(3,5-dimethylpyrazol-1-yl)methane {HC(3,5-Me 2Pz) 3} of the composition [Fe{HC(3,5-Me 2Pz) 3} 2]A m • nH 2O (A = Cl - (I), ClO4 (II), SO 2- 4 (III), CF3SO3 (IV), m = 1, 2, n = 0.1) are synthesized. The compounds are studied by static magnetic susceptibility, IR and diffuse reflectance spectroscopy, and X-ray structure analysis. The crystal structures of two polymorphous modifications of the [Fe{HC(3,5-Me 2Pz) 3} 2](ClO 4) 2 (IIa and IIb) and [Fe{HC(3,5-Me 2Pz) 3} 2](CF 3SO 3) 2 (IV) complexes are determined. The temperature dependence (J. eff(T) shows that the spin crossover 1A1 5T 2 is observed in the polycrystalline phase of complex I and in one of the single-crystal phases of complex II (IIa) and is accompanied by thermochromism (the change of the dark pink color to white).

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