Spectral-kinetics properties of activator emission centers in CsI: Eu

V. Yakovlev, L. Trefilova, A. Karnaukhova, N. Ovcharenko

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

It has been found that only three types of emission centers are responsible for bands at 2.69, 2.78 and 2.67 eV in CsI:Eu crystals grown in vacuum. Within the framework of a suggested model a single dipole Eu2+-v c - is responsible for 2.69 eV band, a two-dipole cluster 2(Eu2+-vc -) for 2.78 eV band and a three-dipole cluster 3(Eu2+-vc -) for 2.67 eV band. The emission at 2.69 and 2.67 eV decays exponentially with time constant 0.42 and 0.9 μs, respectively. The decay kinetics of the emission at 2.78 eV has two exponential components with time constant 0.15 and 0.51 μs. It has been experimentally ascertained that the single dipole, two-dipole and three dipole clusters exist at Eu concentration less than 0.01 mass%; from 0.005 to 0.03 mass% and more than 0.03 mass%, respectively.

Original languageEnglish
Pages (from-to)146-148
Number of pages3
JournalJournal of Luminescence
Volume144
DOIs
Publication statusPublished - 5 Aug 2013

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Vacuum
dipoles
Crystals
Kinetics
kinetics
time constant
decay
vacuum
crystals

Keywords

  • Activator-vacancy dipole
  • Decay kinetics
  • Europium-doped cesium iodide
  • Photoluminescence

ASJC Scopus subject areas

  • Biophysics
  • Atomic and Molecular Physics, and Optics
  • Chemistry(all)
  • Biochemistry
  • Condensed Matter Physics

Cite this

Spectral-kinetics properties of activator emission centers in CsI : Eu. / Yakovlev, V.; Trefilova, L.; Karnaukhova, A.; Ovcharenko, N.

In: Journal of Luminescence, Vol. 144, 05.08.2013, p. 146-148.

Research output: Contribution to journalArticle

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abstract = "It has been found that only three types of emission centers are responsible for bands at 2.69, 2.78 and 2.67 eV in CsI:Eu crystals grown in vacuum. Within the framework of a suggested model a single dipole Eu2+-v c - is responsible for 2.69 eV band, a two-dipole cluster 2(Eu2+-vc -) for 2.78 eV band and a three-dipole cluster 3(Eu2+-vc -) for 2.67 eV band. The emission at 2.69 and 2.67 eV decays exponentially with time constant 0.42 and 0.9 μs, respectively. The decay kinetics of the emission at 2.78 eV has two exponential components with time constant 0.15 and 0.51 μs. It has been experimentally ascertained that the single dipole, two-dipole and three dipole clusters exist at Eu concentration less than 0.01 mass{\%}; from 0.005 to 0.03 mass{\%} and more than 0.03 mass{\%}, respectively.",
keywords = "Activator-vacancy dipole, Decay kinetics, Europium-doped cesium iodide, Photoluminescence",
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AU - Yakovlev, V.

AU - Trefilova, L.

AU - Karnaukhova, A.

AU - Ovcharenko, N.

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N2 - It has been found that only three types of emission centers are responsible for bands at 2.69, 2.78 and 2.67 eV in CsI:Eu crystals grown in vacuum. Within the framework of a suggested model a single dipole Eu2+-v c - is responsible for 2.69 eV band, a two-dipole cluster 2(Eu2+-vc -) for 2.78 eV band and a three-dipole cluster 3(Eu2+-vc -) for 2.67 eV band. The emission at 2.69 and 2.67 eV decays exponentially with time constant 0.42 and 0.9 μs, respectively. The decay kinetics of the emission at 2.78 eV has two exponential components with time constant 0.15 and 0.51 μs. It has been experimentally ascertained that the single dipole, two-dipole and three dipole clusters exist at Eu concentration less than 0.01 mass%; from 0.005 to 0.03 mass% and more than 0.03 mass%, respectively.

AB - It has been found that only three types of emission centers are responsible for bands at 2.69, 2.78 and 2.67 eV in CsI:Eu crystals grown in vacuum. Within the framework of a suggested model a single dipole Eu2+-v c - is responsible for 2.69 eV band, a two-dipole cluster 2(Eu2+-vc -) for 2.78 eV band and a three-dipole cluster 3(Eu2+-vc -) for 2.67 eV band. The emission at 2.69 and 2.67 eV decays exponentially with time constant 0.42 and 0.9 μs, respectively. The decay kinetics of the emission at 2.78 eV has two exponential components with time constant 0.15 and 0.51 μs. It has been experimentally ascertained that the single dipole, two-dipole and three dipole clusters exist at Eu concentration less than 0.01 mass%; from 0.005 to 0.03 mass% and more than 0.03 mass%, respectively.

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