Specific Features of the Microstructure and Properties of Multielement Nitride Coatings Based on TiZrNbAlYCr

Abstract

Multicomponent nanostructured coatings based on (TiZrNbAlYCr)N with a hardness as high as 47 GPa were obtained by cathodic arc deposition. The effect of partial nitrogen pressure P_N (with constant bias potential U_b =–200 V applied to the substrate) on the phase-composition variation, the size of crystallites, and their relation to the microstructure and hardness was investigated. An increase in the nitrogen pressure resulted in the formation of two phases with characteristic BCC (the lattice period is 0.342 nm) and FCC lattices with averaged nanocrystallite sizes of 15 and 2 nm. At a high pressure of 0.5 Pa, crystallites in the FCC phase with a lattice period of 0.437 nm grew in size to ~7 nm. The hardness of deposited coatings with larger (3.5 nm) FCC-phase crystallites and smaller (7 nm) BCC-phase crystallites was enhanced considerably.

Original language	English
Pages (from-to)	98-101
Number of pages	4
Journal	Technical Physics Letters
Volume	44
Issue number	2
DOIs	https://doi.org/10.1134/S1063785018020098
Publication status	Published - 1 Feb 2018
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

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10.1134/S1063785018020098

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@article{cdb402f4f69645c89662136dbe6513e4,

title = "Specific Features of the Microstructure and Properties of Multielement Nitride Coatings Based on TiZrNbAlYCr",

abstract = "Multicomponent nanostructured coatings based on (TiZrNbAlYCr)N with a hardness as high as 47 GPa were obtained by cathodic arc deposition. The effect of partial nitrogen pressure PN (with constant bias potential Ub =–200 V applied to the substrate) on the phase-composition variation, the size of crystallites, and their relation to the microstructure and hardness was investigated. An increase in the nitrogen pressure resulted in the formation of two phases with characteristic BCC (the lattice period is 0.342 nm) and FCC lattices with averaged nanocrystallite sizes of 15 and 2 nm. At a high pressure of 0.5 Pa, crystallites in the FCC phase with a lattice period of 0.437 nm grew in size to ~7 nm. The hardness of deposited coatings with larger (3.5 nm) FCC-phase crystallites and smaller (7 nm) BCC-phase crystallites was enhanced considerably.",

author = "Pogrebnjak, {A. D.} and Beresnev, {V. M.} and Bondar, {O. V.} and Kravchenko, {Ya O.} and B. Zhollybekov and Kupchishin, {A. I.}",

year = "2018",

month = feb,

day = "1",

doi = "10.1134/S1063785018020098",

language = "English",

volume = "44",

pages = "98--101",

journal = "Technical Physics Letters",

issn = "1063-7850",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

TY - JOUR

T1 - Specific Features of the Microstructure and Properties of Multielement Nitride Coatings Based on TiZrNbAlYCr

AU - Pogrebnjak, A. D.

AU - Beresnev, V. M.

AU - Bondar, O. V.

AU - Kravchenko, Ya O.

AU - Zhollybekov, B.

AU - Kupchishin, A. I.

PY - 2018/2/1

Y1 - 2018/2/1

N2 - Multicomponent nanostructured coatings based on (TiZrNbAlYCr)N with a hardness as high as 47 GPa were obtained by cathodic arc deposition. The effect of partial nitrogen pressure PN (with constant bias potential Ub =–200 V applied to the substrate) on the phase-composition variation, the size of crystallites, and their relation to the microstructure and hardness was investigated. An increase in the nitrogen pressure resulted in the formation of two phases with characteristic BCC (the lattice period is 0.342 nm) and FCC lattices with averaged nanocrystallite sizes of 15 and 2 nm. At a high pressure of 0.5 Pa, crystallites in the FCC phase with a lattice period of 0.437 nm grew in size to ~7 nm. The hardness of deposited coatings with larger (3.5 nm) FCC-phase crystallites and smaller (7 nm) BCC-phase crystallites was enhanced considerably.

AB - Multicomponent nanostructured coatings based on (TiZrNbAlYCr)N with a hardness as high as 47 GPa were obtained by cathodic arc deposition. The effect of partial nitrogen pressure PN (with constant bias potential Ub =–200 V applied to the substrate) on the phase-composition variation, the size of crystallites, and their relation to the microstructure and hardness was investigated. An increase in the nitrogen pressure resulted in the formation of two phases with characteristic BCC (the lattice period is 0.342 nm) and FCC lattices with averaged nanocrystallite sizes of 15 and 2 nm. At a high pressure of 0.5 Pa, crystallites in the FCC phase with a lattice period of 0.437 nm grew in size to ~7 nm. The hardness of deposited coatings with larger (3.5 nm) FCC-phase crystallites and smaller (7 nm) BCC-phase crystallites was enhanced considerably.

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