Sol–gel synthesis and characterization of two-component systems based on MgO

Aleksey A. Vedyagin, Ilya V. Mishakov, Timofey M. Karnaukhov, Elena F. Krivoshapkina, Ekaterina V. Ilyina, Tatyana A. Maksimova, Svetlana V. Cherepanova, Pavel V. Krivoshapkin

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Abstract: A series of two-component MOx–MgO systems, where M is Cu, Ni, Co, Fe, Mo or W, was synthesized by sol–gel technique. Aqueous solution of inorganic salt-precursor was used as a hydrolyzing agent. Initial xerogels and final oxides were characterized using X-ray diffraction analysis, scanning electron microscopy and low-temperature nitrogen adsorption. Decomposition of xerogels was studied by differential thermal analysis. According to X-ray diffraction analysis, all xerogel samples are characterized with turbostratic structures regardless of nature of the second component. At the same time, presence of inorganic salt in magnesium hydroxide matrix shifts the temperature of decomposition of latter towards lower values. Structural and textural characteristics of MgO-based oxide systems were found to be strongly affected by the additive. Formation of joint phase was observed in the case of cobalt oxide. In most cases, additives turned out to be even distributed in the bulk of MgO, except for WO3. This oxide formed large agglomerates because of low solubility of precursor. Graphical Abstract: [InlineMediaObject not available: see fulltext.]

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJournal of Sol-Gel Science and Technology
Volume82
Issue number2
DOIs
Publication statusAccepted/In press - 10 Feb 2017

Fingerprint

Xerogels
xerogels
Oxides
X ray diffraction analysis
oxides
synthesis
Magnesium Hydroxide
Salts
salts
Decomposition
decomposition
cobalt oxides
diffraction
Differential thermal analysis
hydroxides
magnesium
thermal analysis
x rays
Nitrogen
solubility

Keywords

  • Characterization
  • MgO
  • Sol–gel synthesis
  • Two-component oxide systems

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Biomaterials
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

Vedyagin, A. A., Mishakov, I. V., Karnaukhov, T. M., Krivoshapkina, E. F., Ilyina, E. V., Maksimova, T. A., ... Krivoshapkin, P. V. (Accepted/In press). Sol–gel synthesis and characterization of two-component systems based on MgO. Journal of Sol-Gel Science and Technology, 82(2), 1-9. https://doi.org/10.1007/s10971-017-4321-3

Sol–gel synthesis and characterization of two-component systems based on MgO. / Vedyagin, Aleksey A.; Mishakov, Ilya V.; Karnaukhov, Timofey M.; Krivoshapkina, Elena F.; Ilyina, Ekaterina V.; Maksimova, Tatyana A.; Cherepanova, Svetlana V.; Krivoshapkin, Pavel V.

In: Journal of Sol-Gel Science and Technology, Vol. 82, No. 2, 10.02.2017, p. 1-9.

Research output: Contribution to journalArticle

Vedyagin, AA, Mishakov, IV, Karnaukhov, TM, Krivoshapkina, EF, Ilyina, EV, Maksimova, TA, Cherepanova, SV & Krivoshapkin, PV 2017, 'Sol–gel synthesis and characterization of two-component systems based on MgO', Journal of Sol-Gel Science and Technology, vol. 82, no. 2, pp. 1-9. https://doi.org/10.1007/s10971-017-4321-3
Vedyagin, Aleksey A. ; Mishakov, Ilya V. ; Karnaukhov, Timofey M. ; Krivoshapkina, Elena F. ; Ilyina, Ekaterina V. ; Maksimova, Tatyana A. ; Cherepanova, Svetlana V. ; Krivoshapkin, Pavel V. / Sol–gel synthesis and characterization of two-component systems based on MgO. In: Journal of Sol-Gel Science and Technology. 2017 ; Vol. 82, No. 2. pp. 1-9.
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AB - Abstract: A series of two-component MOx–MgO systems, where M is Cu, Ni, Co, Fe, Mo or W, was synthesized by sol–gel technique. Aqueous solution of inorganic salt-precursor was used as a hydrolyzing agent. Initial xerogels and final oxides were characterized using X-ray diffraction analysis, scanning electron microscopy and low-temperature nitrogen adsorption. Decomposition of xerogels was studied by differential thermal analysis. According to X-ray diffraction analysis, all xerogel samples are characterized with turbostratic structures regardless of nature of the second component. At the same time, presence of inorganic salt in magnesium hydroxide matrix shifts the temperature of decomposition of latter towards lower values. Structural and textural characteristics of MgO-based oxide systems were found to be strongly affected by the additive. Formation of joint phase was observed in the case of cobalt oxide. In most cases, additives turned out to be even distributed in the bulk of MgO, except for WO3. This oxide formed large agglomerates because of low solubility of precursor. Graphical Abstract: [InlineMediaObject not available: see fulltext.]

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