TY - GEN
T1 - Sol-gel synthesis of chelate containing materials for gas chromatography
AU - Gavrilenko, Mikhail A.
AU - Slizhov, Yurii G.
AU - Faustova, Zhanna V.
AU - Kasymova, Tatiana A.
AU - Gavrilenko, Nataliya Airatovna
PY - 2014
Y1 - 2014
N2 - The adsorption properties of mesoporous chelate containing sorbents which were prepared in two phases with europium and copper acetylacetonate complexes and PEG-115 as surfactant, were evaluated by column experiments. The adsorption properties of mesoporous silica with chelate complexes for some organic compounds were evaluated by gas chromatography. The best separation was achieved for europium acetylacetonate. From specific retention volumes measured at various temperatures the thermodynamic parameters of separation is discussed. Mutual separation of oxygen containing substances could also be demonstrated.
AB - The adsorption properties of mesoporous chelate containing sorbents which were prepared in two phases with europium and copper acetylacetonate complexes and PEG-115 as surfactant, were evaluated by column experiments. The adsorption properties of mesoporous silica with chelate complexes for some organic compounds were evaluated by gas chromatography. The best separation was achieved for europium acetylacetonate. From specific retention volumes measured at various temperatures the thermodynamic parameters of separation is discussed. Mutual separation of oxygen containing substances could also be demonstrated.
KW - Chelate
KW - Gas chromatography
KW - Sorbent
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=84913586291&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84913586291&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/AMR.1040.448
DO - 10.4028/www.scientific.net/AMR.1040.448
M3 - Conference contribution
AN - SCOPUS:84913586291
SN - 9783038352648
VL - 1040
T3 - Advanced Materials Research
SP - 448
EP - 452
BT - Advanced Materials Research
PB - Trans Tech Publications Ltd
T2 - International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014
Y2 - 26 March 2014 through 28 March 2014
ER -