Sol-gel synthesis of chelate containing materials for gas chromatography

Mikhail A. Gavrilenko, Yurii G. Slizhov, Zhanna V. Faustova, Tatiana A. Kasymova, Nataliya Airatovna Gavrilenko

Research output: Chapter in Book/Report/Conference proceedingConference contribution

5 Citations (Scopus)

Abstract

The adsorption properties of mesoporous chelate containing sorbents which were prepared in two phases with europium and copper acetylacetonate complexes and PEG-115 as surfactant, were evaluated by column experiments. The adsorption properties of mesoporous silica with chelate complexes for some organic compounds were evaluated by gas chromatography. The best separation was achieved for europium acetylacetonate. From specific retention volumes measured at various temperatures the thermodynamic parameters of separation is discussed. Mutual separation of oxygen containing substances could also be demonstrated.

Original languageEnglish
Title of host publicationAdvanced Materials Research
PublisherTrans Tech Publications Ltd
Pages448-452
Number of pages5
Volume1040
ISBN (Print)9783038352648
DOIs
Publication statusPublished - 2014
EventInternational Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014 - Tomsk, Russian Federation
Duration: 26 Mar 201428 Mar 2014

Publication series

NameAdvanced Materials Research
Volume1040
ISSN (Print)10226680
ISSN (Electronic)16628985

Other

OtherInternational Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014
CountryRussian Federation
CityTomsk
Period26.3.1428.3.14

Keywords

  • Chelate
  • Gas chromatography
  • Sorbent
  • Synthesis

ASJC Scopus subject areas

  • Engineering(all)

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  • Cite this

    Gavrilenko, M. A., Slizhov, Y. G., Faustova, Z. V., Kasymova, T. A., & Gavrilenko, N. A. (2014). Sol-gel synthesis of chelate containing materials for gas chromatography. In Advanced Materials Research (Vol. 1040, pp. 448-452). (Advanced Materials Research; Vol. 1040). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/AMR.1040.448