Abstract
Literature sources on metal-organic materials encapsulating versatile porphyrinoids and heme enzymes have been discussed in this review. General fundamentals and structural and chemical requisites of these architectures are discussed in introduction followed by historical perspectives of the initial composites. We have categorized the structural aspects of this class of compounds according to the host and guest skeletons as well as encapsulating strategies in a sequential manner. Heme mimetic, as well as some novel applications of the materials including oxidation, electron transfer, carbene transfer and bio-molecule sensing, are then discussed and compared with each other and their homogeneous analogues based on mechanistic similarities, wherever possible.
| Original language | English |
|---|---|
| Pages (from-to) | 135-163 |
| Number of pages | 29 |
| Journal | Coordination Chemistry Reviews |
| Volume | 326 |
| DOIs | |
| Publication status | Published - 1 Nov 2016 |
| Externally published | Yes |
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Keywords
- Catalysis
- Encapsulation
- Heme enzyme
- Metal-organic material
- Porph@MOM
- Porphyrin
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Snapshots of encapsulated porphyrins and heme enzymes in metal-organic materials : A prevailing paradigm of heme mimicry. / Chakraborty, Jeet; Nath, Ipsita; Verpoort, Francis Walter Cornelius.
In: Coordination Chemistry Reviews, Vol. 326, 01.11.2016, p. 135-163.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Snapshots of encapsulated porphyrins and heme enzymes in metal-organic materials
T2 - A prevailing paradigm of heme mimicry
AU - Chakraborty, Jeet
AU - Nath, Ipsita
AU - Verpoort, Francis Walter Cornelius
PY - 2016/11/1
Y1 - 2016/11/1
N2 - Literature sources on metal-organic materials encapsulating versatile porphyrinoids and heme enzymes have been discussed in this review. General fundamentals and structural and chemical requisites of these architectures are discussed in introduction followed by historical perspectives of the initial composites. We have categorized the structural aspects of this class of compounds according to the host and guest skeletons as well as encapsulating strategies in a sequential manner. Heme mimetic, as well as some novel applications of the materials including oxidation, electron transfer, carbene transfer and bio-molecule sensing, are then discussed and compared with each other and their homogeneous analogues based on mechanistic similarities, wherever possible.
AB - Literature sources on metal-organic materials encapsulating versatile porphyrinoids and heme enzymes have been discussed in this review. General fundamentals and structural and chemical requisites of these architectures are discussed in introduction followed by historical perspectives of the initial composites. We have categorized the structural aspects of this class of compounds according to the host and guest skeletons as well as encapsulating strategies in a sequential manner. Heme mimetic, as well as some novel applications of the materials including oxidation, electron transfer, carbene transfer and bio-molecule sensing, are then discussed and compared with each other and their homogeneous analogues based on mechanistic similarities, wherever possible.
KW - Catalysis
KW - Encapsulation
KW - Heme enzyme
KW - Metal-organic material
KW - Porph@MOM
KW - Porphyrin
UR - http://www.scopus.com/inward/record.url?scp=84983036085&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84983036085&partnerID=8YFLogxK
U2 - 10.1016/j.ccr.2016.08.006
DO - 10.1016/j.ccr.2016.08.006
M3 - Review article
AN - SCOPUS:84983036085
VL - 326
SP - 135
EP - 163
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
ER -