Smart recycling of PET to sorbents for insecticides through in situ MOF growth

Abstract

The continually growing level of ecotoxicants generates a request for principal new strategies to safeguard the environment. In this contribution, we proposed a comprehensive approach to solving two emerging problems: recycling polyethylene terephthalate wastes (PET) and removing toxic insecticides from water. The developed technology consumed PET bottles as the source and support for the growth of UiO-66 frameworks and were further applied for the removal of imidacloprid from water. The prepared material was characterized by a range of microscopic and spectroscopic techniques confirming the high loading and homogenous distribution of UiO-66 across the PET support. The sorbent (PET@UiO-66) delivered considerable technical advantages beyond the convenient sorbents: sustainable and cheap preparation; high adsorption capacity and rate; stability and recyclability; 100 times enhanced permeability compared to UiO-66 powder; and applicability in fixed-bed columns. We believe that the proposed design and technological relevance will be a basis for the further developing of the smart utilization of wastes for sustainable functional materials.

Original language	English
Article number	100910
Journal	Applied Materials Today
Volume	22
DOIs	https://doi.org/10.1016/j.apmt.2020.100910
Publication status	Published - Mar 2021

Keywords

Adsorption
Imidacloprid removal
Metal-organic frameworks
Permeability
Polyethylene terephthalate waste

ASJC Scopus subject areas

Materials Science(all)

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10.1016/j.apmt.2020.100910

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Smart recycling of PET to sorbents for insecticides through in situ MOF growth. / Semyonov, Oleg; Chaemchuen, Somboon; Ivanov, Alexey ; Verpoort, Francis; Kolska, Zdenka; Syrtanov, Maxim; Svorcik, Vaclav; Yusubov, Mekhman S.; Lyutakov, Oleksiy ; Guselnikova, Olga ; Postnikov, Pavel S.

In: Applied Materials Today, Vol. 22, 100910, 03.2021.

Research output: Contribution to journal › Article › peer-review

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abstract = "The continually growing level of ecotoxicants generates a request for principal new strategies to safeguard the environment. In this contribution, we proposed a comprehensive approach to solving two emerging problems: recycling polyethylene terephthalate wastes (PET) and removing toxic insecticides from water. The developed technology consumed PET bottles as the source and support for the growth of UiO-66 frameworks and were further applied for the removal of imidacloprid from water. The prepared material was characterized by a range of microscopic and spectroscopic techniques confirming the high loading and homogenous distribution of UiO-66 across the PET support. The sorbent (PET@UiO-66) delivered considerable technical advantages beyond the convenient sorbents: sustainable and cheap preparation; high adsorption capacity and rate; stability and recyclability; 100 times enhanced permeability compared to UiO-66 powder; and applicability in fixed-bed columns. We believe that the proposed design and technological relevance will be a basis for the further developing of the smart utilization of wastes for sustainable functional materials.",

keywords = "Adsorption, Imidacloprid removal, Metal-organic frameworks, Permeability, Polyethylene terephthalate waste",

author = "Oleg Semyonov and Somboon Chaemchuen and Alexey Ivanov and Francis Verpoort and Zdenka Kolska and Maxim Syrtanov and Vaclav Svorcik and Yusubov, {Mekhman S.} and Oleksiy Lyutakov and Olga Guselnikova and Postnikov, {Pavel S.}",

note = "Funding Information: This work was supported by RFBR , project number 19–33–90212 . Research was carried out using the core facilities of TPU's “Physics and Chemical methods of analysis” Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

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doi = "10.1016/j.apmt.2020.100910",

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AU - Semyonov, Oleg

AU - Chaemchuen, Somboon

AU - Ivanov, Alexey

AU - Verpoort, Francis

AU - Kolska, Zdenka

AU - Syrtanov, Maxim

AU - Svorcik, Vaclav

AU - Yusubov, Mekhman S.

AU - Lyutakov, Oleksiy

AU - Guselnikova, Olga

AU - Postnikov, Pavel S.

N1 - Funding Information: This work was supported by RFBR , project number 19–33–90212 . Research was carried out using the core facilities of TPU's “Physics and Chemical methods of analysis” Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2021/3

Y1 - 2021/3

N2 - The continually growing level of ecotoxicants generates a request for principal new strategies to safeguard the environment. In this contribution, we proposed a comprehensive approach to solving two emerging problems: recycling polyethylene terephthalate wastes (PET) and removing toxic insecticides from water. The developed technology consumed PET bottles as the source and support for the growth of UiO-66 frameworks and were further applied for the removal of imidacloprid from water. The prepared material was characterized by a range of microscopic and spectroscopic techniques confirming the high loading and homogenous distribution of UiO-66 across the PET support. The sorbent (PET@UiO-66) delivered considerable technical advantages beyond the convenient sorbents: sustainable and cheap preparation; high adsorption capacity and rate; stability and recyclability; 100 times enhanced permeability compared to UiO-66 powder; and applicability in fixed-bed columns. We believe that the proposed design and technological relevance will be a basis for the further developing of the smart utilization of wastes for sustainable functional materials.

AB - The continually growing level of ecotoxicants generates a request for principal new strategies to safeguard the environment. In this contribution, we proposed a comprehensive approach to solving two emerging problems: recycling polyethylene terephthalate wastes (PET) and removing toxic insecticides from water. The developed technology consumed PET bottles as the source and support for the growth of UiO-66 frameworks and were further applied for the removal of imidacloprid from water. The prepared material was characterized by a range of microscopic and spectroscopic techniques confirming the high loading and homogenous distribution of UiO-66 across the PET support. The sorbent (PET@UiO-66) delivered considerable technical advantages beyond the convenient sorbents: sustainable and cheap preparation; high adsorption capacity and rate; stability and recyclability; 100 times enhanced permeability compared to UiO-66 powder; and applicability in fixed-bed columns. We believe that the proposed design and technological relevance will be a basis for the further developing of the smart utilization of wastes for sustainable functional materials.

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