Abstract
The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation.
| Original language | English |
|---|---|
| Title of host publication | Advanced Materials Research |
| Publisher | Trans Tech Publications Ltd |
| Pages | 155-160 |
| Number of pages | 6 |
| Volume | 1040 |
| ISBN (Print) | 9783038352648 |
| DOIs | |
| Publication status | Published - 2014 |
| Event | International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014 - Tomsk, Russian Federation Duration: 26 Mar 2014 → 28 Mar 2014 |
Publication series
| Name | Advanced Materials Research |
|---|---|
| Volume | 1040 |
| ISSN (Print) | 10226680 |
| ISSN (Electronic) | 16628985 |
Other
| Other | International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 26.3.14 → 28.3.14 |
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Keywords
- High-temperature Sintering
- NiO/YSZ Anode
- Porous Ni-Al Alloy
- Solid Oxide Fuel Cells
ASJC Scopus subject areas
- Engineering(all)
Cite this
Sintering of nio/ysz anode layers for metal-supported solid oxide fuel cell. / Solovyev, A. A.; Ionov, Igor Vyacheslavovich; Kovalchuk, Anastasia Nikolaevna; Kirdyashkin, A. I.; Maznoy, A. S.; Kitler, V. D.
Advanced Materials Research. Vol. 1040 Trans Tech Publications Ltd, 2014. p. 155-160 (Advanced Materials Research; Vol. 1040).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Sintering of nio/ysz anode layers for metal-supported solid oxide fuel cell
AU - Solovyev, A. A.
AU - Ionov, Igor Vyacheslavovich
AU - Kovalchuk, Anastasia Nikolaevna
AU - Kirdyashkin, A. I.
AU - Maznoy, A. S.
AU - Kitler, V. D.
PY - 2014
Y1 - 2014
N2 - The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation.
AB - The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation.
KW - High-temperature Sintering
KW - NiO/YSZ Anode
KW - Porous Ni-Al Alloy
KW - Solid Oxide Fuel Cells
UR - http://www.scopus.com/inward/record.url?scp=84913570737&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84913570737&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/AMR.1040.155
DO - 10.4028/www.scientific.net/AMR.1040.155
M3 - Conference contribution
AN - SCOPUS:84913570737
SN - 9783038352648
VL - 1040
T3 - Advanced Materials Research
SP - 155
EP - 160
BT - Advanced Materials Research
PB - Trans Tech Publications Ltd
ER -