Abstract
Porous ceramics ZrO2-MgO with a 50 vol. % pore volume and bimodal pore size distribution were studied. The samples were produced by cold uniaxial pressing followed by sintering at temperature of 1600°C and a holding time from 10 min to 10 hours. Bimodal pore structure was obtained by adding of ultrahigh molecular weight polyethylene pore-forming particles with average size 50 μm to the initial powder mixtures. The pore volume for all samples was constant - 50±3 vol. %. With increasing of sintering holding time the average size of the macropores decreased and the micropores increased. The coherent diffraction domains average size of components increases with increasing of MgO concentration and the time of the sintering, while the microdistortions of crystal lattice decrease. With an increase of the sintering holding time more than 5 hours, an insufficient stabilization of cubic ZrO2 takes place for the low MgO concentrations. The dependences of the tensile strength and the Young's modulus on the microstresses in the ceramic composite structure are investigated. Estimation of the microstresses on the basis of X-ray diffraction analysis has shown that the tensile strength mainly determined by microstresses and its increasing leads to a strength decrease.
| Original language | English |
|---|---|
| Title of host publication | Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures |
| Editors | Vasily M. Fomin, Victor E. Panin, Sergey G. Psakhie |
| Publisher | American Institute of Physics Inc. |
| Volume | 2051 |
| ISBN (Electronic) | 9780735417779 |
| DOIs | |
| Publication status | Published - 12 Dec 2018 |
| Event | International Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 - Tomsk, Russian Federation Duration: 1 Oct 2018 → 5 Oct 2018 |
Conference
| Conference | International Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 1.10.18 → 5.10.18 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
Sintering and mechanical properties of oxide-oxide composite based on ZrO2-MgO mixtures. / Buyakov, A. S.; Buyakova, S. P.; Tkachev, D. A.; Kulkov, S. N.
Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures. ed. / Vasily M. Fomin; Victor E. Panin; Sergey G. Psakhie. Vol. 2051 American Institute of Physics Inc., 2018. 020046.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Sintering and mechanical properties of oxide-oxide composite based on ZrO2-MgO mixtures
AU - Buyakov, A. S.
AU - Buyakova, S. P.
AU - Tkachev, D. A.
AU - Kulkov, S. N.
PY - 2018/12/12
Y1 - 2018/12/12
N2 - Porous ceramics ZrO2-MgO with a 50 vol. % pore volume and bimodal pore size distribution were studied. The samples were produced by cold uniaxial pressing followed by sintering at temperature of 1600°C and a holding time from 10 min to 10 hours. Bimodal pore structure was obtained by adding of ultrahigh molecular weight polyethylene pore-forming particles with average size 50 μm to the initial powder mixtures. The pore volume for all samples was constant - 50±3 vol. %. With increasing of sintering holding time the average size of the macropores decreased and the micropores increased. The coherent diffraction domains average size of components increases with increasing of MgO concentration and the time of the sintering, while the microdistortions of crystal lattice decrease. With an increase of the sintering holding time more than 5 hours, an insufficient stabilization of cubic ZrO2 takes place for the low MgO concentrations. The dependences of the tensile strength and the Young's modulus on the microstresses in the ceramic composite structure are investigated. Estimation of the microstresses on the basis of X-ray diffraction analysis has shown that the tensile strength mainly determined by microstresses and its increasing leads to a strength decrease.
AB - Porous ceramics ZrO2-MgO with a 50 vol. % pore volume and bimodal pore size distribution were studied. The samples were produced by cold uniaxial pressing followed by sintering at temperature of 1600°C and a holding time from 10 min to 10 hours. Bimodal pore structure was obtained by adding of ultrahigh molecular weight polyethylene pore-forming particles with average size 50 μm to the initial powder mixtures. The pore volume for all samples was constant - 50±3 vol. %. With increasing of sintering holding time the average size of the macropores decreased and the micropores increased. The coherent diffraction domains average size of components increases with increasing of MgO concentration and the time of the sintering, while the microdistortions of crystal lattice decrease. With an increase of the sintering holding time more than 5 hours, an insufficient stabilization of cubic ZrO2 takes place for the low MgO concentrations. The dependences of the tensile strength and the Young's modulus on the microstresses in the ceramic composite structure are investigated. Estimation of the microstresses on the basis of X-ray diffraction analysis has shown that the tensile strength mainly determined by microstresses and its increasing leads to a strength decrease.
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UR - http://www.scopus.com/inward/citedby.url?scp=85059025988&partnerID=8YFLogxK
U2 - 10.1063/1.5083289
DO - 10.1063/1.5083289
M3 - Conference contribution
VL - 2051
BT - Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures
A2 - Fomin, Vasily M.
A2 - Panin, Victor E.
A2 - Psakhie, Sergey G.
PB - American Institute of Physics Inc.
ER -