Silica, alumina and ceria supported Au-Cu nanoparticles prepared via the decomposition of [Au(en)2]2[Cu(C2O 4)2]3·8H2O single-source precursor: Synthesis, characterization and catalytic performance in CO PROX

D. I. Potemkin, E. Yu Semitut, Yu V. Shubin, P. E. Plyusnin, P. V. Snytnikov, E. V. Makotchenko, D. Yu Osadchii, D. A. Svintsitskiy, S. A. Venyaminov, S. V. Korenev, V. A. Sobyanin

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Silica, alumina and ceria supported bimetallic Au-Cu catalysts were prepared via the decomposition of [Au(en)2]2[Cu(C 2O4)2]3·8H2O double complex salt inside the support pore structure. XRD and TEM analyses indicated the selective formation of supported Au0.4Cu0.6 alloy nanoparticles with preset stoichiometry on the support surface. Catalysts were tested in CO preferential oxidation (PROX) reaction. Au 0.4Cu0.6/CeO2 catalyst showed best characteristics having higher CO consumption at higher selectivity in the realistic hydrogen-rich mixture containing CO2 and H2O, compared with Au/CeO2 catalyst.

Original languageEnglish
Pages (from-to)103-111
Number of pages9
JournalCatalysis Today
Volume235
DOIs
Publication statusPublished - 15 Oct 2014
Externally publishedYes

Fingerprint

Aluminum Oxide
Cerium compounds
Carbon Monoxide
Silicon Dioxide
Alumina
Silica
Nanoparticles
Decomposition
Oxidation
Catalysts
Pore structure
Catalyst supports
Stoichiometry
Hydrogen
Salts
Transmission electron microscopy

Keywords

  • Alloy nanoparticles
  • Au-Cu catalysts
  • Bimetallic nanoparticles
  • Double complex salts
  • Gold-copper catalysts
  • Preferential CO oxidation

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Silica, alumina and ceria supported Au-Cu nanoparticles prepared via the decomposition of [Au(en)2]2[Cu(C2O 4)2]3·8H2O single-source precursor : Synthesis, characterization and catalytic performance in CO PROX. / Potemkin, D. I.; Semitut, E. Yu; Shubin, Yu V.; Plyusnin, P. E.; Snytnikov, P. V.; Makotchenko, E. V.; Osadchii, D. Yu; Svintsitskiy, D. A.; Venyaminov, S. A.; Korenev, S. V.; Sobyanin, V. A.

In: Catalysis Today, Vol. 235, 15.10.2014, p. 103-111.

Research output: Contribution to journalArticle

Potemkin, DI, Semitut, EY, Shubin, YV, Plyusnin, PE, Snytnikov, PV, Makotchenko, EV, Osadchii, DY, Svintsitskiy, DA, Venyaminov, SA, Korenev, SV & Sobyanin, VA 2014, 'Silica, alumina and ceria supported Au-Cu nanoparticles prepared via the decomposition of [Au(en)2]2[Cu(C2O 4)2]3·8H2O single-source precursor: Synthesis, characterization and catalytic performance in CO PROX', Catalysis Today, vol. 235, pp. 103-111. https://doi.org/10.1016/j.cattod.2014.04.026
Potemkin, D. I. ; Semitut, E. Yu ; Shubin, Yu V. ; Plyusnin, P. E. ; Snytnikov, P. V. ; Makotchenko, E. V. ; Osadchii, D. Yu ; Svintsitskiy, D. A. ; Venyaminov, S. A. ; Korenev, S. V. ; Sobyanin, V. A. / Silica, alumina and ceria supported Au-Cu nanoparticles prepared via the decomposition of [Au(en)2]2[Cu(C2O 4)2]3·8H2O single-source precursor : Synthesis, characterization and catalytic performance in CO PROX. In: Catalysis Today. 2014 ; Vol. 235. pp. 103-111.
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