TY - JOUR
T1 - Separation of alkali metals
AU - Tikhomirov, I. A.
AU - Orlov, A. A.
AU - Vidyaev, D. G.
PY - 2003/6/1
Y1 - 2003/6/1
N2 - A new gallam-exchange technique for separation of alkali metals was developed. The alkali metal separation factors were determined for the gallam-exchange systems LiGa-NaOH, LiGa-KOH, and KGa-NaOH. The effect of temperature and concentration of the exchanging phases on the separation factors were studied for the systems LiGa-NaOH and LiGa-KOH. Kinetic parameters of lithium, sodium, and potassium element exchanges were determined. The properties of gallam-exchange and amalgam-exchange systems were compared.
AB - A new gallam-exchange technique for separation of alkali metals was developed. The alkali metal separation factors were determined for the gallam-exchange systems LiGa-NaOH, LiGa-KOH, and KGa-NaOH. The effect of temperature and concentration of the exchanging phases on the separation factors were studied for the systems LiGa-NaOH and LiGa-KOH. Kinetic parameters of lithium, sodium, and potassium element exchanges were determined. The properties of gallam-exchange and amalgam-exchange systems were compared.
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U2 - 10.1023/A:1026343019205
DO - 10.1023/A:1026343019205
M3 - Article
AN - SCOPUS:3442878132
VL - 76
SP - 859
EP - 862
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 6
ER -