SELECTION OF INDICATOR ELECTRODE FOR THE DETERMINATION OF OSMIUM BY STRIPPING VOLTAMMETRY.

Abstract

This work compared the electrochemical reduction of osmium graphite, glassy-carbon, and gold electrodes in order to develop a procedure for the stripping-voltammetric (SV) determination of osmium in industrial objects. Under the experimental conditions used, the relative error of measurements made on a platinum electrode exceeds 25%; this prevents its use for the determination of osmium by SV. The voltammograms were taken on an LP-9 polarograph by using a linear change of the electrode potential (v equals 0. 05 V/sec). An electrolyzer with exchangeable beakers was used in the work.

Original language	English
Pages (from-to)	1067-1070
Number of pages	4
Journal	Industrial Laboratory
Volume	52
Issue number	12
Publication status	Published - Dec 1986

ASJC Scopus subject areas

Engineering(all)

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title = "SELECTION OF INDICATOR ELECTRODE FOR THE DETERMINATION OF OSMIUM BY STRIPPING VOLTAMMETRY.",

abstract = "This work compared the electrochemical reduction of osmium graphite, glassy-carbon, and gold electrodes in order to develop a procedure for the stripping-voltammetric (SV) determination of osmium in industrial objects. Under the experimental conditions used, the relative error of measurements made on a platinum electrode exceeds 25%; this prevents its use for the determination of osmium by SV. The voltammograms were taken on an LP-9 polarograph by using a linear change of the electrode potential (v equals 0. 05 V/sec). An electrolyzer with exchangeable beakers was used in the work.",

author = "Kolpakova, {N. A.} and Shvets, {L. A.}",

year = "1986",

month = dec,

language = "English",

volume = "52",

pages = "1067--1070",

journal = "Journal of Parenteral and Enteral Nutrition",

issn = "0148-6071",

publisher = "Cambridge International Science Publishing",

number = "12",

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AU - Kolpakova, N. A.

AU - Shvets, L. A.

PY - 1986/12

Y1 - 1986/12

N2 - This work compared the electrochemical reduction of osmium graphite, glassy-carbon, and gold electrodes in order to develop a procedure for the stripping-voltammetric (SV) determination of osmium in industrial objects. Under the experimental conditions used, the relative error of measurements made on a platinum electrode exceeds 25%; this prevents its use for the determination of osmium by SV. The voltammograms were taken on an LP-9 polarograph by using a linear change of the electrode potential (v equals 0. 05 V/sec). An electrolyzer with exchangeable beakers was used in the work.

AB - This work compared the electrochemical reduction of osmium graphite, glassy-carbon, and gold electrodes in order to develop a procedure for the stripping-voltammetric (SV) determination of osmium in industrial objects. Under the experimental conditions used, the relative error of measurements made on a platinum electrode exceeds 25%; this prevents its use for the determination of osmium by SV. The voltammograms were taken on an LP-9 polarograph by using a linear change of the electrode potential (v equals 0. 05 V/sec). An electrolyzer with exchangeable beakers was used in the work.

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IS - 12

ER -

SELECTION OF INDICATOR ELECTRODE FOR THE DETERMINATION OF OSMIUM BY STRIPPING VOLTAMMETRY.

Abstract

ASJC Scopus subject areas

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