Ruthenium Pincer Complexes

Synthesis and Catalytic Applications

Hussein A. Younus, Wei Su, Nazir Ahmad, Si Chen, Francis Walter Cornelius Verpoort

Research output: Contribution to journalArticle

80 Citations (Scopus)

Abstract

Pincer-based catalysts possess an exceptional balance of stability versus reactivity, aspects of fundamental interest in catalyst design. This balance has been well-controlled by systematic ligand modifications along with the variation of the metal center. Ruthenium pincer complexes (RPCs), exhibit a versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. A large number of novel and valuable reactions has been developed using both stoichiometric and catalytic amounts of RPCs. Compared to the traditional ruthenium catalysts, pincer complexes often present high efficiency, selectivity and functional group tolerance. This review highlights different methodologies for the synthesis of RPCs and their catalytic applications for different reactions reported in the last decade. Additionally, the factors affecting the catalytic reactivity of the RPCs and the reaction mechanisms are discussed.

Original languageEnglish
JournalAdvanced Synthesis and Catalysis
DOIs
Publication statusAccepted/In press - 2015
Externally publishedYes

Fingerprint

Ruthenium
Catalysts
Catalyst selectivity
Functional groups
Metals
Ligands

Keywords

  • Dehydrogenative oxidation
  • Hydrogen transfer
  • Hydrogenation
  • Pincer ligands
  • Ruthenium pincer complexes

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

Cite this

Ruthenium Pincer Complexes : Synthesis and Catalytic Applications. / Younus, Hussein A.; Su, Wei; Ahmad, Nazir; Chen, Si; Verpoort, Francis Walter Cornelius.

In: Advanced Synthesis and Catalysis, 2015.

Research output: Contribution to journalArticle

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