Abstract
The infrared spectral regions of the P-D stretching fundamental band v2 and the first overtone band 2v2 of PH2D were recorded with a resolution of 2.7 × 10-3 and 6.8 × 10-3 cm-1, respectively. In the analysis about 710 and 440 transitions were assigned to the v2 and 2v2 bands. These provided 358 and 268 upper rovibrational energy terms, respectively. Resonance interactions between the states (010000) and (000200) were taken into account in the Hamiltonian used to fit upper energies of the (010000) state. The rovibrational energies of the (020000) state were fitted with a Hamiltonian for an isolated vibrational state.
| Original language | English |
|---|---|
| Pages (from-to) | 288-297 |
| Number of pages | 10 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 217 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Jan 2003 |
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Keywords
- PHD molecule
- Spectroscopic parameters
- Vibration-rotation spectra
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Cite this
Rovibrational analysis of the v2 and 2v2 P-D stretching bands of PH2D. / Ulenikov, O. N.; Khabibulina, O. L.; Bekhtereva, E. S.; Bürger, H.; Jerzembeck, W.
In: Journal of Molecular Spectroscopy, Vol. 217, No. 2, 01.01.2003, p. 288-297.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rovibrational analysis of the v2 and 2v2 P-D stretching bands of PH2D
AU - Ulenikov, O. N.
AU - Khabibulina, O. L.
AU - Bekhtereva, E. S.
AU - Bürger, H.
AU - Jerzembeck, W.
PY - 2003/1/1
Y1 - 2003/1/1
N2 - The infrared spectral regions of the P-D stretching fundamental band v2 and the first overtone band 2v2 of PH2D were recorded with a resolution of 2.7 × 10-3 and 6.8 × 10-3 cm-1, respectively. In the analysis about 710 and 440 transitions were assigned to the v2 and 2v2 bands. These provided 358 and 268 upper rovibrational energy terms, respectively. Resonance interactions between the states (010000) and (000200) were taken into account in the Hamiltonian used to fit upper energies of the (010000) state. The rovibrational energies of the (020000) state were fitted with a Hamiltonian for an isolated vibrational state.
AB - The infrared spectral regions of the P-D stretching fundamental band v2 and the first overtone band 2v2 of PH2D were recorded with a resolution of 2.7 × 10-3 and 6.8 × 10-3 cm-1, respectively. In the analysis about 710 and 440 transitions were assigned to the v2 and 2v2 bands. These provided 358 and 268 upper rovibrational energy terms, respectively. Resonance interactions between the states (010000) and (000200) were taken into account in the Hamiltonian used to fit upper energies of the (010000) state. The rovibrational energies of the (020000) state were fitted with a Hamiltonian for an isolated vibrational state.
KW - PHD molecule
KW - Spectroscopic parameters
KW - Vibration-rotation spectra
UR - http://www.scopus.com/inward/record.url?scp=0037304771&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037304771&partnerID=8YFLogxK
U2 - 10.1016/S0022-2852(02)00059-0
DO - 10.1016/S0022-2852(02)00059-0
M3 - Article
VL - 217
SP - 288
EP - 297
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -